Preprints
https://doi.org/10.5194/egusphere-2025-3250
https://doi.org/10.5194/egusphere-2025-3250
13 Oct 2025
 | 13 Oct 2025

Short-Lived Halogen Sources and Chemistry in the Community Earth System Model v2 (CESM2-SLH)

Rafael Pedro Fernandez, Carlos Alberto Cuevas, Julián Villamayor, Aryeh Feinberg, Douglas E. Kinnison, Francis Vitt, Adriana Bossolasco, Javier A. Barrera, Amelia Reynoso, Orlando G. Tomazzeli, Qinyi Li, and Alfonso Saiz-Lopez

Abstract. The implementation of short-lived halogen (SLH) sources and atmospheric chemistry in the Community Earth System Model v1 (CESM1), has extended the capabilities of this state-of-the-art model to study how SLH chemistry alters the oxidative capacity of the atmosphere and, consequently, the Earth’s climate. In this manuscript, we summarize 15 years of research and developments of SLH chemistry in CESM1 and present a complete revision of the porting of the original SLH implementation into the latest released version of CESM (v2), hereafter CESM2-SLH. This includes a detailed description of all offline and online sources of organic and inorganic SLH, as well as the gas-phase and heterogeneous recycling of chlorine, bromine and iodine in the troposphere and stratosphere, including their species-independent atmospheric sinks. In doing so, we provide a comprehensive evaluation of how changes in model parameters and coupled dynamics within the Community Atmosphere Model v6 (CAM6) affect SLH abundances and their implications. The new CESM2-SLH implementation offers various component sets (compsets) and resolutions, all of which result in equivalent global budgets and zonal distributions of organic and inorganic chlorine, bromine and iodine, which in turn, lead to SLH impacts on atmospheric composition that are consistent with previous CESM1 results. The released CESM2-SLH version includes specific namelist options, input files and technical notes detailing the most important SLH updates implemented over the CESM2/CAM6 routines. Our results show that the global tropospheric burden and tropical stratospheric injection of organic and inorganic chlorine, bromine and iodine species in CESM2-SLH are in agreement with observational assessments and previous modelling studies using CESM1, resulting in significant reductions in global ozone abundance (−21–28 % at the surface, −17–22 % in the troposphere and −2–3 % in the stratosphere) as well as in OH and NO2 (ranging between −2–9 % and −1–10 %, respectively), depending on the specific model configuration and resolution. Based on this, we encourage the wider CESM community to consider the released CESM2-SLH scheme to obtain a more realistic representation of the background influence of natural and anthropogenic short-lived halogen sources and chemistry in air quality and Earth’s climate studies.

Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. While Copernicus Publications makes every effort to include appropriate place names, the final responsibility lies with the authors. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.
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Journal article(s) based on this preprint

05 Oct 2026
Short-lived halogen sources and chemistry in the Community Earth System Model v2 (CESM2-SLH)
Rafael P. Fernandez, Carlos A. Cuevas, Julián Villamayor, Aryeh Feinberg, Douglas E. Kinnison, Francis Vitt, Adriana Bossolasco, Javier A. Barrera, Amelia Reynoso, Orlando G. Tomazzeli, Qinyi Li, and Alfonso Saiz-Lopez
Geosci. Model Dev., 19, 9325–9376, https://doi.org/10.5194/gmd-19-9325-2026,https://doi.org/10.5194/gmd-19-9325-2026, 2026
Short summary
Rafael Pedro Fernandez, Carlos Alberto Cuevas, Julián Villamayor, Aryeh Feinberg, Douglas E. Kinnison, Francis Vitt, Adriana Bossolasco, Javier A. Barrera, Amelia Reynoso, Orlando G. Tomazzeli, Qinyi Li, and Alfonso Saiz-Lopez

Interactive discussion

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2025-3250', Anonymous Referee #1, 08 Dec 2025
    • AC1: 'Reply on RC1', Rafael Pedro Fernandez, 15 May 2026
  • RC2: 'Comment on egusphere-2025-3250', Anonymous Referee #2, 12 Dec 2025
    • AC2: 'Reply on RC2', Rafael Pedro Fernandez, 15 May 2026

Peer review completion

AR – Author's response | RR – Referee report | ED – Editor decision | EF – Editorial file upload
AR by Rafael Pedro Fernandez on behalf of the Authors (15 May 2026)  Manuscript 
EF by Polina Shvedko (19 May 2026)  Author's response   Author's tracked changes   Supplement 
ED: Referee Nomination & Report Request started (10 Jun 2026) by Patrick Jöckel
RR by Anonymous Referee #2 (23 Jun 2026)
RR by Anonymous Referee #1 (29 Jun 2026)
ED: Publish subject to minor revisions (review by editor) (30 Jun 2026) by Patrick Jöckel
AR by Rafael Pedro Fernandez on behalf of the Authors (10 Jul 2026)  Author's response   Author's tracked changes   Manuscript 
ED: Publish as is (24 Jul 2026) by Patrick Jöckel
AR by Rafael Pedro Fernandez on behalf of the Authors (24 Jul 2026)

Post-review adjustments

AA – Author's adjustment | EA – Editor approval
AA by Rafael Pedro Fernandez on behalf of the Authors (24 Sep 2026)   Author's adjustment   Manuscript
EA: Adjustments approved (24 Sep 2026) by Patrick Jöckel

Interactive discussion

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2025-3250', Anonymous Referee #1, 08 Dec 2025
    • AC1: 'Reply on RC1', Rafael Pedro Fernandez, 15 May 2026
  • RC2: 'Comment on egusphere-2025-3250', Anonymous Referee #2, 12 Dec 2025
    • AC2: 'Reply on RC2', Rafael Pedro Fernandez, 15 May 2026

Peer review completion

AR – Author's response | RR – Referee report | ED – Editor decision | EF – Editorial file upload
AR by Rafael Pedro Fernandez on behalf of the Authors (15 May 2026)  Manuscript 
EF by Polina Shvedko (19 May 2026)  Author's response   Author's tracked changes   Supplement 
ED: Referee Nomination & Report Request started (10 Jun 2026) by Patrick Jöckel
RR by Anonymous Referee #2 (23 Jun 2026)
RR by Anonymous Referee #1 (29 Jun 2026)
ED: Publish subject to minor revisions (review by editor) (30 Jun 2026) by Patrick Jöckel
AR by Rafael Pedro Fernandez on behalf of the Authors (10 Jul 2026)  Author's response   Author's tracked changes   Manuscript 
ED: Publish as is (24 Jul 2026) by Patrick Jöckel
AR by Rafael Pedro Fernandez on behalf of the Authors (24 Jul 2026)

Post-review adjustments

AA – Author's adjustment | EA – Editor approval
AA by Rafael Pedro Fernandez on behalf of the Authors (24 Sep 2026)   Author's adjustment   Manuscript
EA: Adjustments approved (24 Sep 2026) by Patrick Jöckel

Journal article(s) based on this preprint

05 Oct 2026
Short-lived halogen sources and chemistry in the Community Earth System Model v2 (CESM2-SLH)
Rafael P. Fernandez, Carlos A. Cuevas, Julián Villamayor, Aryeh Feinberg, Douglas E. Kinnison, Francis Vitt, Adriana Bossolasco, Javier A. Barrera, Amelia Reynoso, Orlando G. Tomazzeli, Qinyi Li, and Alfonso Saiz-Lopez
Geosci. Model Dev., 19, 9325–9376, https://doi.org/10.5194/gmd-19-9325-2026,https://doi.org/10.5194/gmd-19-9325-2026, 2026
Short summary
Rafael Pedro Fernandez, Carlos Alberto Cuevas, Julián Villamayor, Aryeh Feinberg, Douglas E. Kinnison, Francis Vitt, Adriana Bossolasco, Javier A. Barrera, Amelia Reynoso, Orlando G. Tomazzeli, Qinyi Li, and Alfonso Saiz-Lopez
Rafael Pedro Fernandez, Carlos Alberto Cuevas, Julián Villamayor, Aryeh Feinberg, Douglas E. Kinnison, Francis Vitt, Adriana Bossolasco, Javier A. Barrera, Amelia Reynoso, Orlando G. Tomazzeli, Qinyi Li, and Alfonso Saiz-Lopez

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Latest update: 05 Oct 2026
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Short summary
In this work we summarize 15 years of research and developments of short-lived halogens (SLH) using the Community Earth System Model (CESM) and present a complete description of the implementation and capabilities achieved with the new released version CESM2-SLH, including specific namelist options, input files and technical notes detailing the most important SLH updates that must be considered for the different model configurations and resolutions.
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