Preprints
https://doi.org/10.5194/egusphere-2025-3094
https://doi.org/10.5194/egusphere-2025-3094
25 Jul 2025
 | 25 Jul 2025
Status: this preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).

Measurement report: Observational insights into the impact of dust transport on atmospheric dicarboxylic acids in ground region and free troposphere

Minxia Shen, Weining Qi, Yali Liu, Yifan Zhang, Wenting Dai, Lu Li, Xiao Guo, Yue Cao, Yingkun Jiang, Qian Wang, Shicong Li, Qiyuan Wang, and Jianjun Li

Abstract. This study investigated the vertical distribution of PM2.5 and size-segregated aerosols at the foot and top of Mount Hua in Northwest China, focusing on C2 formation and its δ13C characteristics influenced by dust transport. Under non-dust conditions, PM2.5 and diacids concentrations at the foot were 4.5 and 2.1 times higher than those at the top, with stronger local anthropogenic signals (C9, 5.67 times higher) and pronounced diurnal diacids variation. Higher C2/C4 (5.84 vs. 4.74), C3/C4 (1.04 vs. 0.56) ratios and δ13C values (-21.5 ‰ vs. -27.6 ‰) at the top indicated photochemical aging during aerosol transport. C2 concentration was positively correlated with aerosol liquid water content and its size distribution pattern matched with precursors, confirming aqueous-phase oxidation as the dominant formation pathway. During dust events, PM2.5 concentrations at the foot and top reached 457 μg m−3 and 165 μg m−3, but C2 concentrations in PM2.5 decreased by 59 % (foot) and 25 % (top), while δ13C values of C2 exhibited a significant positive shift (foot: -27.6 ‰ to -23.9 ‰; top: -21.5 ‰ to -13.2 ‰), attributed to alkaline dust catalyzing 13C-enriched oxalate formation. mGly became the second most abundant acid due to enrichment on dust-particle surfaces. Size-segregated data revealed decreased fine-particle C2 but increased coarse-particle C2, elevating the coarse-to-fine ratio from 0.3~0.4 to 0.6~1.1. These findings offer valuable insights into the altitude-dependent transformation of SOA affected by dust transport, enhancing our understanding of mountain atmospheric chemistry and regional air quality.

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Minxia Shen, Weining Qi, Yali Liu, Yifan Zhang, Wenting Dai, Lu Li, Xiao Guo, Yue Cao, Yingkun Jiang, Qian Wang, Shicong Li, Qiyuan Wang, and Jianjun Li

Status: open (until 10 Sep 2025)

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  • RC1: 'Comment on egusphere-2025-3094', Anonymous Referee #1, 07 Aug 2025 reply
  • RC2: 'Comment on egusphere-2025-3094', Anonymous Referee #2, 02 Sep 2025 reply
Minxia Shen, Weining Qi, Yali Liu, Yifan Zhang, Wenting Dai, Lu Li, Xiao Guo, Yue Cao, Yingkun Jiang, Qian Wang, Shicong Li, Qiyuan Wang, and Jianjun Li

Data sets

Measurement reports: Observational Insights into the Impact of Dust Transport on Atmospheric Dicarboxylic Acids in Ground region and Free Troposphere [Data set] L. Jianjun and S. Minxia https://zenodo.org/doi/10.5281/zenodo.15788834

Minxia Shen, Weining Qi, Yali Liu, Yifan Zhang, Wenting Dai, Lu Li, Xiao Guo, Yue Cao, Yingkun Jiang, Qian Wang, Shicong Li, Qiyuan Wang, and Jianjun Li

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Short summary
This study examines how dust transport modulates oxalic acid formation pathways in aerosols across different elevations of Mount Hua. During dust events, oxalic acid and precursors shift from fine to coarse particles, with concurrent heterogeneous reactions on coarse particle surfaces. The characteristic isotopic fractionation signatures accompanying these transformations yield novel theoretical frameworks for elucidating aerosol aging mechanisms in mountainous environments.
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