the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
| 12 Feb 2024
Total Air Content measurements from the RECAP ice core
Abstract. Total air content (TAC) of the REnland ice CAP project (RECAP) core, drilled in summer 2015, is measured as a part of investigating the elevation history of the Greenland Ice Sheet (GIS). TAC is a proxy for the elevation at which the ice was originally formed as the TAC in ice cores is predominantly influenced by surface air pressure and conditions like temperature and local summer insolation. The RECAP TAC data shows incoherently low values in the Holocene climatic optimum (6 to 9 kyr b2k) and in the Eemian (119 to 121 kyr b2k) which renders the TAC data unfit for paleo elevation interpolation. In contrast, the glacial section (11.7 kyr to 119 kyr b2K) has consistent TAC values thus in principle facilitating the past elevation calculations. However, we observe TAC variations related to Dansgaard-Oeschger events (D-O) that cannot originate from elevation changes but must be linked to changes in the firn structure. We analyse the pattern of the structural changes in the RECAP and NGRIP cores. For the melt affected sections (Holocene and Eemian) we use melt affected TAC to reconstruct summer temperatures.
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RC1: 'Comment on egusphere-2024-237', Anonymous Referee #1, 06 Mar 2024
Referee comment for: ‘Total Air Content measurements from the RECAP ice core’, Vudayagiri et al.
This manuscript presents Total Air Content (TAC) measurements throughout the full RECAP ice core from the Renland ice cap, Greenland. The initial aim was to understand the elevation history of the ice cap, as TAC of ice core bubbles can be a proxy for ice elevation given the relationship between elevation and barometric pressure. However, much of the measured record was affected by either melt induced lowering of air content values, or rapid climatic transitions dominating the TAC signal due to non-elevation induced effects on pore volume. The main interpretations therefore presented are a melt correction for the TAC in the Holocene section of the core, and an elevation calculation for a short section of the core in the Last Glacial Maximum which is presumed unaffected by melt or strong climatic changes.
Much analysis has been conducted in this work, and it would be of benefit to see these results published. It is nice to see TAC measurements from two laboratories each with established and robust methodologies, which can demonstrate analytical comparability, especially given the more complex outcomes of the data. The authors have commendably looked for additional interpretation of the data given that much of it could not be used for elevation.
For me, the structure and writing of the paper lacked clarity, making it difficult to follow. The rational of the paper seemed somewhat unclear – the d18O record suggested as an anchor for the hypothesis of no elevation change at Renland isn’t presented or discussed further, and previous studies of Greenland TAC (NGRIP) have shown climatic influences affecting TAC values so I am not clear on how an elevation history was expected to be obtained throughout the whole of RECAP. I am also missing what the wider scientific conclusions of the paper are, for example could there be some discussion on the application of TAC measurements to Greenland cores given the observations in this paper? Everything needs pulling together more succinctly for the reader. In some areas, I would like to see further detail, for example with the age scale and with errors on the different analytical systems used. I give more specific comments below.
Major questions:
Abstract:
The abstract somewhat peters out, not effectively summarising the paper, and I suggest it is rewritten. Given the main goal of the paper was for an elevation study, why does it not give the elevation estimate for the one section of the core which allowed it? The final two sentences state two things that were done in the paper without presenting the result of them. There are no final remarks on the scientific takeaways of this paper. Improving this may help the clarity of the rest of the paper.
Introduction:
Line 28 states that 'the study uses d18O of H2O from the Renland ice cap as an anchor point arguing that the ice cap has not experience significant elevation changes'. However, I could not see this record referenced here or presented in the paper. This should be included. A recent paper by Grieman et al., 2024 present an example of the use of d18O in conjunction with TAC for elevation change, published I note after submission of this paper but a useful reference for the revision. (https://doi.org/10.1038/s41561-024-01375-8).
Section 1.2:
This section would benefit from subheadings to break the text in to defined sections. The discussion on insolation is long for a general overview of the idea; can this be refined? I also think this discussion needs to be connected back to the expected or observed influence of insolation on the RECAP core itself to keep it relevant.
Line 105: It is referenced that the TAC record in the NGRIP core was influenced by D-O events and the conclusion was that climatically stable periods are preferential for elevation estimates. Therefore, why was the rational of the TAC measurements from RECAP to show elevation history of Renland throughout the core, when it would also likely show these same climatic influences over significant periods? Was it expected that you would observe something different?
- Measurements:
TAC from PSU was measured as part of d15N analyses. Given that d15N can be a useful indicator for firn column changes, could this available d15N be helpful in the interpretation? It looks as though lower TAC values coincide with higher d15N in the Supplementary Information plots. The plotted d15N is not mentioned in the main paper, only a data repository link is given – can the main paper refer to these plots, or even include the d15N in a plot in the main paper? I think there is interest here.
What are the errors of the respective analytical systems used at PSU and PICE? I can see final pooled standard deviations of the data but not the errors of the analytical systems themselves.
- Results and Discussion:
The TAC data are reported to be presented on the RECAP GICC05 age scale, but the reference for this seems to be incorrect; the Simonsen 2018 paper does not appear to discuss an age scale. Please replace with appropriate citation or included some detail on the age scale in this paper.
Is the existing RECAP GICC05 age scale an ice age scale only, or did it include an existing gas age scale? I am not clear on whether this paper has constructed their own gas age scale. If the latter, can the gas age scale please be presented somewhere? For clarity, it would also be helpful if it could be stated somewhere which data are presented on which of these two age scales.
- Conclusions:
I would like to see the concluding section bring together the investigations of the paper more effectively. I am missing final remarks on the wider scientific impact of this paper – for example given the results of this paper, what are the suggestions for future TAC analysis in other Greenland cores?
Minor/technical points:
Abstract: Suggest changing TAC ‘is’ a proxy to TAC ‘can be’ a proxy, in the complications of the proxy and the context of the results of this paper.
Line 23: Can you say why Renland ice cap elevation stability is a pertinent question?
Line 39: at an elevation ‘of’ 2315 m a.s.l. … near ‘the’ summit.
Line 54: total air content has been defined already so can just be TAC, also missing a comma after TAC.
Line 71: Can you clarify whether the parameter you use is the one with or the one without the later additional sites?
Line 105: This it the first mention of Dansgaard-Oeschger events in the main text I think, define ‘D-O’ here since it is used herein.
Line 189: ‘The temperature effect will be below 1%’ – can you explain or reference this value?
Line 191: (in) TAC
Line 199: Line scan(ning)
Line 203: Line scan(ner)
Figure 4: The top step-plot of melt % does not appear to have an axis. Please amend this.
Lines 225 – 228: This has been directly copied and pasted from the Appendix which it refers to (or vice versa, since I notice the same section in Appendix A still self-refers to Appendix A. Please reword one to avoid repetition and remove self-reference in Appendix.
Numbering of subsections is incorrect after 4.2.
Line 279-286: Again this section is directly copy and pasted from/to the Supplement so needs re-writing. In both sections, ‘Why this is the case we ignore’ seems quite a negative phrasing to me, perhaps it just a preference but I would ask to change this. You don’t explain this further because you don’t believe it impacts your results, or because you do not know the explanation?
Line 307: ‘outlined’ rather than ‘lined out’
Supplement:
The supplement needs a thorough proofread by the authors for the present grammar/typing errors.
S1: Is the bubble size determined by eye looking at the photos with the scale? If so, does this have quite a large error?
Figure S8: Difficult to read this figure at the size presented.
‘DO-events’ is used in the supplement, while it is ‘D-O events’ in the main text. Should be the same for consistency.
Citation: https://doi.org/10.5194/egusphere-2024-237-RC1 - AC2: 'Reply on RC1', Thomas Blunier, 24 May 2024
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RC2: 'Comment on egusphere-2024-237', Anonymous Referee #2, 07 Apr 2024
The manuscript by Vudayagiri et al. present a new Total Air Content (TAC) record measured on the RECAP ice core from Greenland and covering the past ~121 000 years. The authors combine TAC dataset measured in two laboratories. The first dataset has been measured using a new experimental set-up dedicated to TAC analyses at PICE, Niels Bohr Institute (Denmark) and the second dataset has been obtained indirectly using the existing experimental set-ups for CH4 and δ15N of N2 analyses at Penn State University (USA). The authors show that it is challenging to use the new TAC record to infer robust information about past elevation changes at RECAP. Still they make an attempt for the last Glacial Maximum and they follow other research directions to extract climatic information from their new record (e.g. melt fraction and amplitude of the warming during the mid-Holocene and at the end of the Last Interglacial) and investigate the controlling factors of both the short- and long- timescale variations in the RECAP TAC record (e.g. firn structure changes, local insolation).
I’m surprised (to say the least) about the shape of this manuscript especially considering the list of experts who worked on it. Indeed, the current manuscript requires some very major revisions both in terms of the form and the content in order to reach a state that is reasonable enough so it can be considered for publication. In fact, I think that it is a real pity that this manuscript is in such poor shape because it is nonetheless very nice to see a new TAC record measured at high resolution on a costal site in Greenland. I think it is important that this new record is eventually published. I also think that the different research directions based on this new records which are presented (but never really fully developed) are interesting and well within the scope of Climate of the Past.
Major comments:
Overall, I found the current manuscript very difficult to read and to understand. I would argue that it is due to the fact that the manuscript contains a number of big problems both related to the form and the content. Indeed:
- I find the form and structure of the manuscript of poor quality. It is written as such that the logic followed for the development of the different paragraphs and the different sections is often hard to grasp, it often lacks of transitions between the paragraphs. In addition, the captions of the figures are not precise enough and the figures themselves often not big enough making hard to see what the authors are describing. I also believe that there are too much important information and calculations, and too many figures that have been placed in the supplementary material (SM), making the reader having to go constantly back and forth between the main manuscript and the SM, this is not ideal.
- In many places, the work performed is either not well described and vague (in several places, background information is missing), or in opposite, sometimes, the information becomes very technical and no background information is provided to help the reader to follow, especially in the case that the reader is not a specialist of this climate proxy. All this makes it very hard to identify properly what the key results coming out of this study are.
- Various research topics related to TAC are being tackled in the manuscript going from investigating the melt fraction based on TAC to reconstruct summer temperature, to using TAC during the Last Glacial Maximum (LGM) to provide information on paleo-elevations, to investigating the link of TAC changes at RECAP with insolation changes, and also how they are affected by the abrupt Dansgaard-Oeschger (DO) events. All these topics are worth looking into but maybe it is too much for one paper? If the authors want indeed to tackle them all, they need to do an important effort to guide thoroughly the readers by providing a more comprehensive introduction providing referenced background context, presenting in both a succinct and precise way the different aspects, announcing the outline of the different following sections etc. Alternatively, the authors could consider refocus their study on only a selection of topics. It could be beneficial to improve the clarity and structure of the paper and it would also prevent having such a large SM.
- In turn, I would like to mention that as far as I understand this is the first time that the experimental system developed at PICE is presented in a publication. As a result, I believe that stronger emphasise should be put on the presentation and the assessment of the new system e.g. no clear description and quantitative estimates of the attached uncertainties is provided. To me, the description of this new experimental system is an important result of the study in itself and it would deserve also to be highlighted, for instance in the abstract and the conclusions of the study.
In the following I provide more detailed comments information related to these main remarks and suggestions for changes. I would strongly recommend the authors to consider them when preparing a new version of their manuscript.
-Abstract:
It needs to be rewritten in order to focus precisely on what is discussed/presented in the paper. Most sentences are very vague. The authors tell us what they investigated but not the actual results found. Here they should highlight for instance what is new compared to other TAC records, what are the quantitative results related to summer temperature reconstructions. Also, if the authors want to mention the paleoelevations estimates for the LGM, they need to also be more specific and provide the actual calculated estimates. It seems to me that the fact that a new experimental set-up for measuring TAC is important and should be also included in the main messages of this abstract.
-Section 1.2, paragraph starting line 74:
This section needs to be revised to follow a linear development as it is very hard to read. It currently jumps from mentioning the short-term variability of Vc to the role of solar insolation on O2/N2 and then the link between local insolation and TAC. This makes it very unclear and it lakes transitions between the paragraphs. A suggestion would be to (1) introduce the fact that there is a link on long timescales between local insolation and TAC, (2) present the parallel between TAC and the O2/N2 ratio and the potential physical mechanisms to explain the link of these tracers to local insolation, (3) next, to mention that based TAC has been used for constraining through orbital dating the latest Antarctic reference chronologies (AICC2012 and AICC2023, Bazin et al. 2012; Bouchet et al. 2023), and (4) then present and discuss the fact that TAC is also influenced by short-term climate variations. The authors cite the Eicher et al. (2016) paper but there is also the recent paper by Epifanio et al. (2023).
Section 2:
As mentioned previously and as far as I understand this is the first time that the experimental system developed at PICE is presented in a publication. As a result, I believe that stronger emphasise should be put on the presentation of the system, e.g. it is necessary to add a schematic of the experimental system. Also, it is essential to provide a more substantial description and quantifications of the different sources of uncertainties attached to the measurements and to state the overall uncertainty attached to each analysis of TAC with the new system, e.g. the authors mention briefly the uncertainty related to the calibration of the experimental volume but there are other sources such as the one related to the water vapour pressure evaluation, the mass loss during the time of sample pre-evacuation or the uncertainty related to the measurement of the pressure gauge itself ?
I understand that the PSU experimental protocol has been presented in details elsewhere, however the authors should still state the uncertainty attached to the TAC measurements performed with this system.
In the section 4, the authors provide a pooled standard deviation but (1) I don’t think this is the place to provide this information (this should be done in section 2) and (2) I don’t understand what it represents effectively and what it does and does not account for. This needs to be clarified.
Finally, in my opinion, the presentation of this new system at PICE is an important added value to the paper and hence this could be better highlighted for instance in the abstract and the conclusion of the paper.
Section 3:
The dataset from PSU are corrected for the CBE using a linear regression defined based on the PICE data, this regression needs to be presented more clearly and discussed. I would suspect the depth-interval considered is going to have an impact on the slope of the regression line and hence the values of the CBE corrections for PSU measurements. Figure S3 presents some error interval but no details are provided regarding how this was quantified, this is missing and should be added.
The authors discuss in the supplementary material the agreement between the PICE and PSU dataset. I think this is a shame that it is placed there as this section is very important for the readers to gauge how far it is possible to go into the interpretation of the new records when combined. Also the current discussion is very brief and qualitative, it needs to be revised and more quantitative.
Section 4:
The structure of this section needs to be revised. In particular, before going into the interpretation of the different sections of the record, it is essential that clear presentation and description of the dataset are provided e.g. in term of the amplitude of the signals, their variability and how they compare. And then, a structure of the rest of the section needs to be announced so the reader knows what to expect in the following of the section. The titles of the sub-sections 4.1, 4.2 and 4.3 should also be more specific than just the name of a time period. Also, please check the numbering of the sections, there are some mistakes. For instance, a second section 4.1 (Glacial) comes after section 4.2 (previous Interglacial). That section 4.1 Glacial seems too short to be a section of its own too?
The section related to the identification of the melt layer needs to be re-written so it is easier to follow the reasoning of the authors. They also need to provide some background regarding the identification of the meltlayers and how it is possible to infer some temperature reconstructions from the melt fraction. In fact, how is the melt fraction estimated, what is based on theoretical calculations and what is based on the actual TAC measured values? Has this methodology been applied to other cores and is there any ways that it can be verified by an alternative method? I have to confess that I got lost here… Clearer information should be provided.
Their reconstructions need to be better discussed in the context of the other existing reconstructions such as the ones shown in Figure 4 from Buizert et al. (2018). In the context of their temperature reconstruction and this applies to the whole interval, I think showing the water isotopic profile from RECAP is really missing. I am aware it is challenging to infer robust quantitative temperature reconstruction from water isotopes in Greenland but still it does provide some useful information (e.g. NEEM community members 2013) and it would be very valuable to use it in this context.
I am also wondering about how large the melt layers are? How many TAC data are measured over a melt layer? Could an uncertainty bar be added to the graph in Figure S6?
Section 4.3 (relation to climate changes during DO events):
I find it very difficult to follow the reasoning and what has been done here. The authors need to clarify greatly what they have done both in the main text and the supplement. Amongst other things, in the SM, there is a mention of setting a value of 0.9 to the midpoint of the CH4 increase, I don’t understand this. Also, Figure S8 is way too small, it is not possible to see anything. How was the timing of the start of dust and CH4 increase defined? Was it done visually or what it done using a systematic or statistical method such as done in studies such as Rasmussen et al. 2014 or Erhardt et al. 2019?
In several places in the paper and in this section in particular, the authors mention the delta age changes across the ice core, however they do not provide any quantitative information about it nor about how it has been estimated. More quantitative details should be provided and it would also be good to have a figure showing its evolution. This information could be discussed in the section about the RECAP timescale in the SM.
Section 4.3 (TAC and insolation):
It is unclear to me whether the authors are using the ISI380 curve as the local insolation curve solely because this is the curve used for the EDC TAC record or whether they also proceeded to the evaluation of the threshold by tuning the precession to obliquity amplitude ratio of ISI in the power spectra on the corresponding ratio of TAC and they effectively found that at RECAP 380 W.m-2 was also the appropriate threshold. Note for instance that at NGRIP, Eicher et al. (2016) established that the most appropriate curve for ISI 390. I would like also to point out that in a recent paper, Raynaud et al. (2023) evidence a strong correlation between TAC and the mean half year summer insolation and propose that the latter is a more appropriate orbital curve to use than the ISI380. Indeed, as mentioned previously, the ISI threshold was evaluated by tuning the precession to obliquity amplitude ratio of ISI in the power spectra on the corresponding ratio of TAC. A limitation is that it involves some circular reasoning, as in turn, because of that resemblance ISI380 was used for orbital tuning purposes. Hence, I would suggest the authors to look into the relationship between RECAP TAC data and the mean half year summer insolation instead, the added value is that it is chosen independently from a tuning on the TAC power spectra and it also allows for the change of length of seasons.
Section 4.4:
Considering the large uncertainties attached to the estimate of past elevation of the RECAP site, I would suggest the authors to rephrase their results such as the elevation at the RECAP site did not change significantly between the LGM and today. And hence, their results are coherent with the prime hypothesis that the Renland ice cap did not change elevation through time. Indeed, the authors need to be rigorous in the phrasing of the results: what they did apply to the RECAP site but it is important to stay cautious when extrapolating to the state of the Renland ice cap.
Conclusions:
Please be more quantitative especially regarding the summary of the paleoelevation during the LGM reconstructions. Provide also some perspectives because I feel that a lot of topics are touched upon and it leaves many open questions and opens a lot of doors for subsequent studies. This should be highlighted.
Finally, the authors need to be careful when revising their manuscript: In places, the text is redundant between the main manuscript and the appendix or supplementary material. For instance, the text found between line 278 and line 285 is also found in the supplementary material. Also the text in Appendix A, line 366 to 370 is a copy of the text present in the main manuscript (including a reference to the Appendix itself!).
Other comments:
Line 12: Avoid the use of the term Eemian, and also be more specific that it is only a portion of the Last interglacial that is covered considering that it is represented by the interval 119-121 ka.
Line 36: Revise the title of the section, it is more about the RECAP ice core drilling site than the Renland ice cap; Also in this section, it would be good the add a few sentences related to the position of this drilling site in relation to the old Renland ice core site.
Line 40: What do the authors mean by temperature measured in the firn? Is this estimate an average on the whole firn column? Or is it a measurement done at the surface? Please specify this and how it was measured (presence of a weather station for monitoring over a few years?).
Line 45: Revise the numbering of the supplementary figures, this is the first time the authors refer to a figure and it is numbered S3. Also, add a space between 530 and m.
Line 49: On Figure 1: to add the location of the previous Renland ice core.
Line 94: Ref to Raynaud et al. 2007 is not appropriate in this context.
Line 96: Eicher et al. (2016) use a threshold at 390 W.m-2 and not 320 W.m-2, it needs to be corrected.
Line 173: It is unclear to me if the authors display their record on an ice age scale or a gas age sale, this should be specified.
Line 185: The caption of Figure 2 states that it presents an estimated mean annual renland temperature but it seems to me that it is misleading. As far as I understand the only temperature reconstruction inferred from a Renland ice core is for the section covering the Holocene (Vinther et al. 2009). The older part of the curve is the NGRIP temperature scaled up by 13°K if I understand well because this is the temperature difference between the two sites at the Holocene or present-day ? But surely, this is not reasonable to assume that this offset has been constant through time? The authors need to clarify this and discuss this limitation somewhere. Also, I would suggest to temperature in °C rather than K as usually done in most if not all paleoclimate publications presenting temperature reconstructions, so it is more intuitive.
Line 192: I don’t find this statement correct: the different potential factors contributing to TAC variations in Greenland and Antarctica might be similar but I believe it is still an open question regarding their relative influence, it may change from one ice core site to the other (even within Greenland and Antarctica).
Line 216: Figure 4. Add numbering for the panel and adjust the caption accordingly as well as clarify it. It is currently challenging to understand this figure, what is represented and where do the different variables come from. For instance, amongst other things, I don’t understand the representation of the percentage of melt. Temperatures should also be provided in °C and ideally as anomalies relative to today.
Line 226: Has the model HIRHAM5 been validated at other sites regarding its capability to reconstruct summer temperature from melt information? Please provide information. Please provide information also related to the attached uncertainty and represent it on the figure.
Line 240: Change the title e.g. “TAC changes at the end of the Last interglacial” and please avoid the use of Eemian for the Last interglacial as strictly speaking this is not appropriate when referring to climate changes inferred in ice core records (see discussion in Govin et al. 2015). Also, the record doesn’t quite fully cover the Last Interglacial but effectively only the end.
Line 260: Please clarify the caption of Figure 5 (dust record is in orange and continuous CH4 in red?)
Line 264: Section 4.2 rather than Section 4.3?
Line 279: sentence starting with “As methane…” and the next one: Please provide reference to this statement. This is very unclear, please rephrase. Also you mention that delta age is very variable, plese provide quantified estimate and show the delta age evolution in a figure.
Line 268: Please refer to the figures in the supplement here and consider moving these figures in the main text, they are interesting!
Line 285: Eicher et al. is redundant, remove one of the two references.
Line 294: …than in the NGRIP ice core…
Line 296: Figure 6 is not intuitive and easy to understand, please provide more information to guide the reader in understanding it. Also in the text, the authors do provide timing estimates (e.g. sentence staring line 192), so would it be possible to redo the figure with an x-axis being the time rather than this normalized age with no unit ?
Line 300: Another section 4.3? Please correct the numbering of the section.
Line 347: sea level.
Line 361: please state the actual quantified uncertainty here.
Line 367: It is unclear to me why is the modeling work presented in an appendix and not in the SOM like the other supplementary information.
Supplementary material:
Page 6, S6: Following up on a comment I made above, the authors should consider mentioning the delta age evolution and showing a figure of it in this section.
Page 7, S7.2: to add a caption to the table.
Page 15, S10: the authors mention GS18, GS19.1 and GI23.1. If they want to leave this information, they should highlight them on the Figure S10. However, it doesn’t seem to me that it is relevant since they don’t really discuss these intervals elsewhere.
References:
Bazin et al. CP, 9, 1715, 2013.
Bouchet et al., CP, 19, 2257 ; 2023
Eicher et al. CP, 12, 1979, 2016
Erhardt et al. CP, 15, 811, 2019.
Epifanio et al. TC, https://doi.org/10.5194/tc-17-4837-2023
Govin et al. QSR, 129, 1, 2015.
NEEM project members, Nature, 493, 2013
Rasmussen et al. QSR, 106, 14, 2014.
Citation: https://doi.org/10.5194/egusphere-2024-237-RC2 - AC1: 'Reply on RC2', Thomas Blunier, 24 May 2024
Interactive discussion
Status: closed
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RC1: 'Comment on egusphere-2024-237', Anonymous Referee #1, 06 Mar 2024
Referee comment for: ‘Total Air Content measurements from the RECAP ice core’, Vudayagiri et al.
This manuscript presents Total Air Content (TAC) measurements throughout the full RECAP ice core from the Renland ice cap, Greenland. The initial aim was to understand the elevation history of the ice cap, as TAC of ice core bubbles can be a proxy for ice elevation given the relationship between elevation and barometric pressure. However, much of the measured record was affected by either melt induced lowering of air content values, or rapid climatic transitions dominating the TAC signal due to non-elevation induced effects on pore volume. The main interpretations therefore presented are a melt correction for the TAC in the Holocene section of the core, and an elevation calculation for a short section of the core in the Last Glacial Maximum which is presumed unaffected by melt or strong climatic changes.
Much analysis has been conducted in this work, and it would be of benefit to see these results published. It is nice to see TAC measurements from two laboratories each with established and robust methodologies, which can demonstrate analytical comparability, especially given the more complex outcomes of the data. The authors have commendably looked for additional interpretation of the data given that much of it could not be used for elevation.
For me, the structure and writing of the paper lacked clarity, making it difficult to follow. The rational of the paper seemed somewhat unclear – the d18O record suggested as an anchor for the hypothesis of no elevation change at Renland isn’t presented or discussed further, and previous studies of Greenland TAC (NGRIP) have shown climatic influences affecting TAC values so I am not clear on how an elevation history was expected to be obtained throughout the whole of RECAP. I am also missing what the wider scientific conclusions of the paper are, for example could there be some discussion on the application of TAC measurements to Greenland cores given the observations in this paper? Everything needs pulling together more succinctly for the reader. In some areas, I would like to see further detail, for example with the age scale and with errors on the different analytical systems used. I give more specific comments below.
Major questions:
Abstract:
The abstract somewhat peters out, not effectively summarising the paper, and I suggest it is rewritten. Given the main goal of the paper was for an elevation study, why does it not give the elevation estimate for the one section of the core which allowed it? The final two sentences state two things that were done in the paper without presenting the result of them. There are no final remarks on the scientific takeaways of this paper. Improving this may help the clarity of the rest of the paper.
Introduction:
Line 28 states that 'the study uses d18O of H2O from the Renland ice cap as an anchor point arguing that the ice cap has not experience significant elevation changes'. However, I could not see this record referenced here or presented in the paper. This should be included. A recent paper by Grieman et al., 2024 present an example of the use of d18O in conjunction with TAC for elevation change, published I note after submission of this paper but a useful reference for the revision. (https://doi.org/10.1038/s41561-024-01375-8).
Section 1.2:
This section would benefit from subheadings to break the text in to defined sections. The discussion on insolation is long for a general overview of the idea; can this be refined? I also think this discussion needs to be connected back to the expected or observed influence of insolation on the RECAP core itself to keep it relevant.
Line 105: It is referenced that the TAC record in the NGRIP core was influenced by D-O events and the conclusion was that climatically stable periods are preferential for elevation estimates. Therefore, why was the rational of the TAC measurements from RECAP to show elevation history of Renland throughout the core, when it would also likely show these same climatic influences over significant periods? Was it expected that you would observe something different?
- Measurements:
TAC from PSU was measured as part of d15N analyses. Given that d15N can be a useful indicator for firn column changes, could this available d15N be helpful in the interpretation? It looks as though lower TAC values coincide with higher d15N in the Supplementary Information plots. The plotted d15N is not mentioned in the main paper, only a data repository link is given – can the main paper refer to these plots, or even include the d15N in a plot in the main paper? I think there is interest here.
What are the errors of the respective analytical systems used at PSU and PICE? I can see final pooled standard deviations of the data but not the errors of the analytical systems themselves.
- Results and Discussion:
The TAC data are reported to be presented on the RECAP GICC05 age scale, but the reference for this seems to be incorrect; the Simonsen 2018 paper does not appear to discuss an age scale. Please replace with appropriate citation or included some detail on the age scale in this paper.
Is the existing RECAP GICC05 age scale an ice age scale only, or did it include an existing gas age scale? I am not clear on whether this paper has constructed their own gas age scale. If the latter, can the gas age scale please be presented somewhere? For clarity, it would also be helpful if it could be stated somewhere which data are presented on which of these two age scales.
- Conclusions:
I would like to see the concluding section bring together the investigations of the paper more effectively. I am missing final remarks on the wider scientific impact of this paper – for example given the results of this paper, what are the suggestions for future TAC analysis in other Greenland cores?
Minor/technical points:
Abstract: Suggest changing TAC ‘is’ a proxy to TAC ‘can be’ a proxy, in the complications of the proxy and the context of the results of this paper.
Line 23: Can you say why Renland ice cap elevation stability is a pertinent question?
Line 39: at an elevation ‘of’ 2315 m a.s.l. … near ‘the’ summit.
Line 54: total air content has been defined already so can just be TAC, also missing a comma after TAC.
Line 71: Can you clarify whether the parameter you use is the one with or the one without the later additional sites?
Line 105: This it the first mention of Dansgaard-Oeschger events in the main text I think, define ‘D-O’ here since it is used herein.
Line 189: ‘The temperature effect will be below 1%’ – can you explain or reference this value?
Line 191: (in) TAC
Line 199: Line scan(ning)
Line 203: Line scan(ner)
Figure 4: The top step-plot of melt % does not appear to have an axis. Please amend this.
Lines 225 – 228: This has been directly copied and pasted from the Appendix which it refers to (or vice versa, since I notice the same section in Appendix A still self-refers to Appendix A. Please reword one to avoid repetition and remove self-reference in Appendix.
Numbering of subsections is incorrect after 4.2.
Line 279-286: Again this section is directly copy and pasted from/to the Supplement so needs re-writing. In both sections, ‘Why this is the case we ignore’ seems quite a negative phrasing to me, perhaps it just a preference but I would ask to change this. You don’t explain this further because you don’t believe it impacts your results, or because you do not know the explanation?
Line 307: ‘outlined’ rather than ‘lined out’
Supplement:
The supplement needs a thorough proofread by the authors for the present grammar/typing errors.
S1: Is the bubble size determined by eye looking at the photos with the scale? If so, does this have quite a large error?
Figure S8: Difficult to read this figure at the size presented.
‘DO-events’ is used in the supplement, while it is ‘D-O events’ in the main text. Should be the same for consistency.
Citation: https://doi.org/10.5194/egusphere-2024-237-RC1 - AC2: 'Reply on RC1', Thomas Blunier, 24 May 2024
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RC2: 'Comment on egusphere-2024-237', Anonymous Referee #2, 07 Apr 2024
The manuscript by Vudayagiri et al. present a new Total Air Content (TAC) record measured on the RECAP ice core from Greenland and covering the past ~121 000 years. The authors combine TAC dataset measured in two laboratories. The first dataset has been measured using a new experimental set-up dedicated to TAC analyses at PICE, Niels Bohr Institute (Denmark) and the second dataset has been obtained indirectly using the existing experimental set-ups for CH4 and δ15N of N2 analyses at Penn State University (USA). The authors show that it is challenging to use the new TAC record to infer robust information about past elevation changes at RECAP. Still they make an attempt for the last Glacial Maximum and they follow other research directions to extract climatic information from their new record (e.g. melt fraction and amplitude of the warming during the mid-Holocene and at the end of the Last Interglacial) and investigate the controlling factors of both the short- and long- timescale variations in the RECAP TAC record (e.g. firn structure changes, local insolation).
I’m surprised (to say the least) about the shape of this manuscript especially considering the list of experts who worked on it. Indeed, the current manuscript requires some very major revisions both in terms of the form and the content in order to reach a state that is reasonable enough so it can be considered for publication. In fact, I think that it is a real pity that this manuscript is in such poor shape because it is nonetheless very nice to see a new TAC record measured at high resolution on a costal site in Greenland. I think it is important that this new record is eventually published. I also think that the different research directions based on this new records which are presented (but never really fully developed) are interesting and well within the scope of Climate of the Past.
Major comments:
Overall, I found the current manuscript very difficult to read and to understand. I would argue that it is due to the fact that the manuscript contains a number of big problems both related to the form and the content. Indeed:
- I find the form and structure of the manuscript of poor quality. It is written as such that the logic followed for the development of the different paragraphs and the different sections is often hard to grasp, it often lacks of transitions between the paragraphs. In addition, the captions of the figures are not precise enough and the figures themselves often not big enough making hard to see what the authors are describing. I also believe that there are too much important information and calculations, and too many figures that have been placed in the supplementary material (SM), making the reader having to go constantly back and forth between the main manuscript and the SM, this is not ideal.
- In many places, the work performed is either not well described and vague (in several places, background information is missing), or in opposite, sometimes, the information becomes very technical and no background information is provided to help the reader to follow, especially in the case that the reader is not a specialist of this climate proxy. All this makes it very hard to identify properly what the key results coming out of this study are.
- Various research topics related to TAC are being tackled in the manuscript going from investigating the melt fraction based on TAC to reconstruct summer temperature, to using TAC during the Last Glacial Maximum (LGM) to provide information on paleo-elevations, to investigating the link of TAC changes at RECAP with insolation changes, and also how they are affected by the abrupt Dansgaard-Oeschger (DO) events. All these topics are worth looking into but maybe it is too much for one paper? If the authors want indeed to tackle them all, they need to do an important effort to guide thoroughly the readers by providing a more comprehensive introduction providing referenced background context, presenting in both a succinct and precise way the different aspects, announcing the outline of the different following sections etc. Alternatively, the authors could consider refocus their study on only a selection of topics. It could be beneficial to improve the clarity and structure of the paper and it would also prevent having such a large SM.
- In turn, I would like to mention that as far as I understand this is the first time that the experimental system developed at PICE is presented in a publication. As a result, I believe that stronger emphasise should be put on the presentation and the assessment of the new system e.g. no clear description and quantitative estimates of the attached uncertainties is provided. To me, the description of this new experimental system is an important result of the study in itself and it would deserve also to be highlighted, for instance in the abstract and the conclusions of the study.
In the following I provide more detailed comments information related to these main remarks and suggestions for changes. I would strongly recommend the authors to consider them when preparing a new version of their manuscript.
-Abstract:
It needs to be rewritten in order to focus precisely on what is discussed/presented in the paper. Most sentences are very vague. The authors tell us what they investigated but not the actual results found. Here they should highlight for instance what is new compared to other TAC records, what are the quantitative results related to summer temperature reconstructions. Also, if the authors want to mention the paleoelevations estimates for the LGM, they need to also be more specific and provide the actual calculated estimates. It seems to me that the fact that a new experimental set-up for measuring TAC is important and should be also included in the main messages of this abstract.
-Section 1.2, paragraph starting line 74:
This section needs to be revised to follow a linear development as it is very hard to read. It currently jumps from mentioning the short-term variability of Vc to the role of solar insolation on O2/N2 and then the link between local insolation and TAC. This makes it very unclear and it lakes transitions between the paragraphs. A suggestion would be to (1) introduce the fact that there is a link on long timescales between local insolation and TAC, (2) present the parallel between TAC and the O2/N2 ratio and the potential physical mechanisms to explain the link of these tracers to local insolation, (3) next, to mention that based TAC has been used for constraining through orbital dating the latest Antarctic reference chronologies (AICC2012 and AICC2023, Bazin et al. 2012; Bouchet et al. 2023), and (4) then present and discuss the fact that TAC is also influenced by short-term climate variations. The authors cite the Eicher et al. (2016) paper but there is also the recent paper by Epifanio et al. (2023).
Section 2:
As mentioned previously and as far as I understand this is the first time that the experimental system developed at PICE is presented in a publication. As a result, I believe that stronger emphasise should be put on the presentation of the system, e.g. it is necessary to add a schematic of the experimental system. Also, it is essential to provide a more substantial description and quantifications of the different sources of uncertainties attached to the measurements and to state the overall uncertainty attached to each analysis of TAC with the new system, e.g. the authors mention briefly the uncertainty related to the calibration of the experimental volume but there are other sources such as the one related to the water vapour pressure evaluation, the mass loss during the time of sample pre-evacuation or the uncertainty related to the measurement of the pressure gauge itself ?
I understand that the PSU experimental protocol has been presented in details elsewhere, however the authors should still state the uncertainty attached to the TAC measurements performed with this system.
In the section 4, the authors provide a pooled standard deviation but (1) I don’t think this is the place to provide this information (this should be done in section 2) and (2) I don’t understand what it represents effectively and what it does and does not account for. This needs to be clarified.
Finally, in my opinion, the presentation of this new system at PICE is an important added value to the paper and hence this could be better highlighted for instance in the abstract and the conclusion of the paper.
Section 3:
The dataset from PSU are corrected for the CBE using a linear regression defined based on the PICE data, this regression needs to be presented more clearly and discussed. I would suspect the depth-interval considered is going to have an impact on the slope of the regression line and hence the values of the CBE corrections for PSU measurements. Figure S3 presents some error interval but no details are provided regarding how this was quantified, this is missing and should be added.
The authors discuss in the supplementary material the agreement between the PICE and PSU dataset. I think this is a shame that it is placed there as this section is very important for the readers to gauge how far it is possible to go into the interpretation of the new records when combined. Also the current discussion is very brief and qualitative, it needs to be revised and more quantitative.
Section 4:
The structure of this section needs to be revised. In particular, before going into the interpretation of the different sections of the record, it is essential that clear presentation and description of the dataset are provided e.g. in term of the amplitude of the signals, their variability and how they compare. And then, a structure of the rest of the section needs to be announced so the reader knows what to expect in the following of the section. The titles of the sub-sections 4.1, 4.2 and 4.3 should also be more specific than just the name of a time period. Also, please check the numbering of the sections, there are some mistakes. For instance, a second section 4.1 (Glacial) comes after section 4.2 (previous Interglacial). That section 4.1 Glacial seems too short to be a section of its own too?
The section related to the identification of the melt layer needs to be re-written so it is easier to follow the reasoning of the authors. They also need to provide some background regarding the identification of the meltlayers and how it is possible to infer some temperature reconstructions from the melt fraction. In fact, how is the melt fraction estimated, what is based on theoretical calculations and what is based on the actual TAC measured values? Has this methodology been applied to other cores and is there any ways that it can be verified by an alternative method? I have to confess that I got lost here… Clearer information should be provided.
Their reconstructions need to be better discussed in the context of the other existing reconstructions such as the ones shown in Figure 4 from Buizert et al. (2018). In the context of their temperature reconstruction and this applies to the whole interval, I think showing the water isotopic profile from RECAP is really missing. I am aware it is challenging to infer robust quantitative temperature reconstruction from water isotopes in Greenland but still it does provide some useful information (e.g. NEEM community members 2013) and it would be very valuable to use it in this context.
I am also wondering about how large the melt layers are? How many TAC data are measured over a melt layer? Could an uncertainty bar be added to the graph in Figure S6?
Section 4.3 (relation to climate changes during DO events):
I find it very difficult to follow the reasoning and what has been done here. The authors need to clarify greatly what they have done both in the main text and the supplement. Amongst other things, in the SM, there is a mention of setting a value of 0.9 to the midpoint of the CH4 increase, I don’t understand this. Also, Figure S8 is way too small, it is not possible to see anything. How was the timing of the start of dust and CH4 increase defined? Was it done visually or what it done using a systematic or statistical method such as done in studies such as Rasmussen et al. 2014 or Erhardt et al. 2019?
In several places in the paper and in this section in particular, the authors mention the delta age changes across the ice core, however they do not provide any quantitative information about it nor about how it has been estimated. More quantitative details should be provided and it would also be good to have a figure showing its evolution. This information could be discussed in the section about the RECAP timescale in the SM.
Section 4.3 (TAC and insolation):
It is unclear to me whether the authors are using the ISI380 curve as the local insolation curve solely because this is the curve used for the EDC TAC record or whether they also proceeded to the evaluation of the threshold by tuning the precession to obliquity amplitude ratio of ISI in the power spectra on the corresponding ratio of TAC and they effectively found that at RECAP 380 W.m-2 was also the appropriate threshold. Note for instance that at NGRIP, Eicher et al. (2016) established that the most appropriate curve for ISI 390. I would like also to point out that in a recent paper, Raynaud et al. (2023) evidence a strong correlation between TAC and the mean half year summer insolation and propose that the latter is a more appropriate orbital curve to use than the ISI380. Indeed, as mentioned previously, the ISI threshold was evaluated by tuning the precession to obliquity amplitude ratio of ISI in the power spectra on the corresponding ratio of TAC. A limitation is that it involves some circular reasoning, as in turn, because of that resemblance ISI380 was used for orbital tuning purposes. Hence, I would suggest the authors to look into the relationship between RECAP TAC data and the mean half year summer insolation instead, the added value is that it is chosen independently from a tuning on the TAC power spectra and it also allows for the change of length of seasons.
Section 4.4:
Considering the large uncertainties attached to the estimate of past elevation of the RECAP site, I would suggest the authors to rephrase their results such as the elevation at the RECAP site did not change significantly between the LGM and today. And hence, their results are coherent with the prime hypothesis that the Renland ice cap did not change elevation through time. Indeed, the authors need to be rigorous in the phrasing of the results: what they did apply to the RECAP site but it is important to stay cautious when extrapolating to the state of the Renland ice cap.
Conclusions:
Please be more quantitative especially regarding the summary of the paleoelevation during the LGM reconstructions. Provide also some perspectives because I feel that a lot of topics are touched upon and it leaves many open questions and opens a lot of doors for subsequent studies. This should be highlighted.
Finally, the authors need to be careful when revising their manuscript: In places, the text is redundant between the main manuscript and the appendix or supplementary material. For instance, the text found between line 278 and line 285 is also found in the supplementary material. Also the text in Appendix A, line 366 to 370 is a copy of the text present in the main manuscript (including a reference to the Appendix itself!).
Other comments:
Line 12: Avoid the use of the term Eemian, and also be more specific that it is only a portion of the Last interglacial that is covered considering that it is represented by the interval 119-121 ka.
Line 36: Revise the title of the section, it is more about the RECAP ice core drilling site than the Renland ice cap; Also in this section, it would be good the add a few sentences related to the position of this drilling site in relation to the old Renland ice core site.
Line 40: What do the authors mean by temperature measured in the firn? Is this estimate an average on the whole firn column? Or is it a measurement done at the surface? Please specify this and how it was measured (presence of a weather station for monitoring over a few years?).
Line 45: Revise the numbering of the supplementary figures, this is the first time the authors refer to a figure and it is numbered S3. Also, add a space between 530 and m.
Line 49: On Figure 1: to add the location of the previous Renland ice core.
Line 94: Ref to Raynaud et al. 2007 is not appropriate in this context.
Line 96: Eicher et al. (2016) use a threshold at 390 W.m-2 and not 320 W.m-2, it needs to be corrected.
Line 173: It is unclear to me if the authors display their record on an ice age scale or a gas age sale, this should be specified.
Line 185: The caption of Figure 2 states that it presents an estimated mean annual renland temperature but it seems to me that it is misleading. As far as I understand the only temperature reconstruction inferred from a Renland ice core is for the section covering the Holocene (Vinther et al. 2009). The older part of the curve is the NGRIP temperature scaled up by 13°K if I understand well because this is the temperature difference between the two sites at the Holocene or present-day ? But surely, this is not reasonable to assume that this offset has been constant through time? The authors need to clarify this and discuss this limitation somewhere. Also, I would suggest to temperature in °C rather than K as usually done in most if not all paleoclimate publications presenting temperature reconstructions, so it is more intuitive.
Line 192: I don’t find this statement correct: the different potential factors contributing to TAC variations in Greenland and Antarctica might be similar but I believe it is still an open question regarding their relative influence, it may change from one ice core site to the other (even within Greenland and Antarctica).
Line 216: Figure 4. Add numbering for the panel and adjust the caption accordingly as well as clarify it. It is currently challenging to understand this figure, what is represented and where do the different variables come from. For instance, amongst other things, I don’t understand the representation of the percentage of melt. Temperatures should also be provided in °C and ideally as anomalies relative to today.
Line 226: Has the model HIRHAM5 been validated at other sites regarding its capability to reconstruct summer temperature from melt information? Please provide information. Please provide information also related to the attached uncertainty and represent it on the figure.
Line 240: Change the title e.g. “TAC changes at the end of the Last interglacial” and please avoid the use of Eemian for the Last interglacial as strictly speaking this is not appropriate when referring to climate changes inferred in ice core records (see discussion in Govin et al. 2015). Also, the record doesn’t quite fully cover the Last Interglacial but effectively only the end.
Line 260: Please clarify the caption of Figure 5 (dust record is in orange and continuous CH4 in red?)
Line 264: Section 4.2 rather than Section 4.3?
Line 279: sentence starting with “As methane…” and the next one: Please provide reference to this statement. This is very unclear, please rephrase. Also you mention that delta age is very variable, plese provide quantified estimate and show the delta age evolution in a figure.
Line 268: Please refer to the figures in the supplement here and consider moving these figures in the main text, they are interesting!
Line 285: Eicher et al. is redundant, remove one of the two references.
Line 294: …than in the NGRIP ice core…
Line 296: Figure 6 is not intuitive and easy to understand, please provide more information to guide the reader in understanding it. Also in the text, the authors do provide timing estimates (e.g. sentence staring line 192), so would it be possible to redo the figure with an x-axis being the time rather than this normalized age with no unit ?
Line 300: Another section 4.3? Please correct the numbering of the section.
Line 347: sea level.
Line 361: please state the actual quantified uncertainty here.
Line 367: It is unclear to me why is the modeling work presented in an appendix and not in the SOM like the other supplementary information.
Supplementary material:
Page 6, S6: Following up on a comment I made above, the authors should consider mentioning the delta age evolution and showing a figure of it in this section.
Page 7, S7.2: to add a caption to the table.
Page 15, S10: the authors mention GS18, GS19.1 and GI23.1. If they want to leave this information, they should highlight them on the Figure S10. However, it doesn’t seem to me that it is relevant since they don’t really discuss these intervals elsewhere.
References:
Bazin et al. CP, 9, 1715, 2013.
Bouchet et al., CP, 19, 2257 ; 2023
Eicher et al. CP, 12, 1979, 2016
Erhardt et al. CP, 15, 811, 2019.
Epifanio et al. TC, https://doi.org/10.5194/tc-17-4837-2023
Govin et al. QSR, 129, 1, 2015.
NEEM project members, Nature, 493, 2013
Rasmussen et al. QSR, 106, 14, 2014.
Citation: https://doi.org/10.5194/egusphere-2024-237-RC2 - AC1: 'Reply on RC2', Thomas Blunier, 24 May 2024
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Sindhu Vudayagiri
Bo Vinther
Johannes Freitag
Peter L. Langen
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