Measurement report: Investigation of Optical Properties of Different Fuels Diesel Exhaust by an Atmospheric Simulation Chamber experiment 

Abstract. This study investigates the optical properties and variability of the mass absorption coefficient (MAC) of carbonaceous aerosols produced by the combustion of different fuels. Emissions were also characterized in terms of particle size distribution and concentrations of elemental (EC) and organic carbon (OC). Experiments were conducted in an atmospheric simulation chamber with a soot generator fueled with propane and a commercial diesel engine running on regular diesel and Hydrotreated Vegetable Oil (HVO). Different methods of sampling and analyzing carbonaceous aerosols were evaluated, focusing on workplace environments. The EC:TC (total carbon) ratios were found to be around 0.7 for propane, 0.15 for diesel, and 0.4 for HVO, indicating a higher proportion of OC in the diesel and HVO samples. Fresh soot particles showed monomodal log-normal distributions with peaks varying based on the fuel type and combustion process, with propane particles exhibiting a peak at larger particle sizes compared to HVO and diesel. The optical properties revealed that the MAC values varied across different fuel exhausts. Diesel combustion produced more light-absorbing particles compared to propane and HVO, with MAC values measured between 870 and 635 nm ranging from 6.2 ± 0.5 to 9.4 ± 0.4 m² g⁻¹ for commercial diesel, 5.2 ± 0.5 to 7.8 ± 1.1 m² g⁻¹ for propane, and 5.8 ± 0.2 to 8.4 ± 0.6 m² g⁻¹ for HVO.