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Preprints
https://doi.org/10.5194/egusphere-2024-3468
https://doi.org/10.5194/egusphere-2024-3468
11 Dec 2024
 | 11 Dec 2024

Source-explicit estimation of brown carbon in the polluted atmosphere over North China Plain: implications for distribution, absorption and direct radiative effect

Jiamao Zhou, Jiarui Wu, Xiaoli Su, Ruonan Wang, Xia Li, Qian Jiang, Ting Zhang, Wenting Dai, Junji Cao, Xuexi Tie, and Guohui Li

Abstract. Brown carbon (BrC) is recognized as a considerable factor changing the atmospheric radiation balance. In addition to the biomass and biofuel sources, both field observations and laboratory studies suggest that fossil fuel combustion is an important contributor to BrC. This highlights a critical gap in the treatment of BrC in climate models, which typically categorize organic aerosols (OA) from fossil fuels as non-absorbing or simplistically assume that all OA are light-scattering. Here we present a regional simulation of BrC during a highly polluted winter in North China Plain (NCP) by using the WRF-Chem model incorporating currently known BrC sources with explicit absorption properties. The modified model generally performs well in simulating air pollutants and aerosols species against observations. Our simulations show that the average near-surface mass concentration of BrC in the NCP is 4.8 μg m-3 and its contribution to the aerosol absorption optical depth at 365 nm is 11.2 %. A diagnostic adjoint method has been used to quantify the overall direct radiative effect (DRE) of BrC and contributions from various sources. We find that the DRE of BrC is predominantly negative with an average of -0.10 W m-2 at the top of the atmosphere (TOA) over the NCP, and consequently decreases the direct radiative cooling effect of OA by 24.0 % with a TOA warming of up to +0.34 W m-2. Our findings reveal that residential coal combustion is the principal contributor to the DRE of BrC in the NCP, and a noteworthy contribution from secondary BrC.

Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this preprint. The responsibility to include appropriate place names lies with the authors.
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Short summary
Brown carbon (BrC) is a type of airborne particle produced from various combustion sources which...
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