Preprints
https://doi.org/10.5194/egusphere-2024-2667
https://doi.org/10.5194/egusphere-2024-2667
04 Sep 2024
 | 04 Sep 2024

Aerosol trace element solubility and deposition fluxes over the polluted, dusty Mediterranean and Black Sea basins

Rachel Ursula Shelley, Alexander Roberts Baker, Max Thomas, and Sam Murphy

Abstract. Aerosol samples collected during summer 2013 on GEOTRACES cruise GA04 in the Mediterranean and Black seas were analysed for their soluble and total metal and major ion composition. The fractional solubilities (soluble / total concentrations) of the lithogenic elements (Al, Ti, Mn, Fe, Co, Th) varied strongly with atmospheric dust loading. Solubilities of these elements in samples that contained high concentrations of mineral dust were noticeably lower than at equivalent dust concentrations over the Atlantic Ocean. This behaviour probably reflects the distinct transport and pollutant regimes of the Mediterranean basin. Elements with more intense anthropogenic sources (P, V, Ni, Cu, Zn, Cd, Pb) had a variety of largely independent sources in the region and generally displayed higher fractional solubilities than the lithogenic elements. Calculated dry deposition fluxes showed a west to east decline in the N/P ratio in deposition over the Mediterranean, a factor that contributes to the P-limited status of the eastern basin. Atmospheric deposition may make a significant contribution to the surface water budgets of Mn and Zn in the western Mediterranean.

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Rachel Ursula Shelley, Alexander Roberts Baker, Max Thomas, and Sam Murphy

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2024-2667', Anonymous Referee #1, 02 Oct 2024
  • RC2: 'Comment on egusphere-2024-2667', Karine Desboeufs, 06 Oct 2024
  • RC3: 'Comment on egusphere-2024-2667', Anonymous Referee #3, 22 Oct 2024

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2024-2667', Anonymous Referee #1, 02 Oct 2024
  • RC2: 'Comment on egusphere-2024-2667', Karine Desboeufs, 06 Oct 2024
  • RC3: 'Comment on egusphere-2024-2667', Anonymous Referee #3, 22 Oct 2024
Rachel Ursula Shelley, Alexander Roberts Baker, Max Thomas, and Sam Murphy
Rachel Ursula Shelley, Alexander Roberts Baker, Max Thomas, and Sam Murphy

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Short summary
The fractions of trace elements in atmospheric particles over the Mediterranean and Black seas that are soluble have been measured. These soluble fractions can affect the growth of microorganisms in the ocean and our results show that they are affected by mixing with pollutants from the surrounding land and shipping emissions. Atmospheric particles contribute to the soluble element loads found in the Mediterranean surface waters and influence the balance between nitrogen and phosphorus there.