Vertical profiles and surface distributions of trace gases (CO, O₃, NO, NO₂) in the Arctic wintertime boundary layer using low-cost sensors during ALPACA-2022

Abstract. Electrochemical gas sensors (EGSs) have been used to measure the surface distributions and vertical profiles of trace gases in the wintertime Arctic Boundary Layer during the Alaskan Layered Pollution and Chemical Analysis (ALPACA) field experiment in Fairbanks, Alaska in January–February 2022. The MICRO sensors for MEasurements of GASes (MICROMEGAS) instrument set up with CO, NO, NO₂ and O₃ EGSs was operated on the ground at an outdoor reference site downtown Fairbanks for calibration, onboard a vehicle moving through the city and its surroundings and onboard a tethered balloon, the Helikite, at a site at the edge of the city. To calibrate the measurements, a set of machine learning (ML) calibration methods were tested. For each method, learning and prediction were performed with coincident MICROMEGAS and reference analyser measurements at the downtown site. For CO, the calibration parameters provided by the manufacturer led to the best agreement between the EGS and the reference analyser and no ML method was needed for calibration. The correlation coefficient R is 0.82 and the slope of the linear regression between MICROMEGAS and reference data is 1.12. The mean bias is not significant but the Root Mean Square Error (290 ppbv) is rather large because of CO concentrations reaching several ppmv downtown Fairbanks. For NO, NO₂ and O₃, the best agreements for the prediction datasets were obtained with an artificial neural network, the Multi-Layer Perceptron. For these 3 gases, the correlation coefficients are higher than 0.95 and the slopes of linear regressions with the reference data are in the range 0.93–1.04. The mean biases which are 1±3 ppbv, 0±4 ppbv and 3±12 ppbv for NO₂, O₃ and NO respectively are not significant. Measurements from the car round of January 21 are presented to highlight the ability of MICROMEGAS to quantify the surface variability of the target trace gases in Fairbanks and the surrounding hills. MICROMEGAS flew 11 times from the ground up to a maximum of 350 m a.g.l. onboard the Helikite at the site at the edge of the city. The statistics performed over the Helikite MICROMEGAS dataset show that the median vertical gas profiles are characterised by almost constant mixing ratios. The median values over the vertical are 140, 8, 4 and 32 ppbv for CO, NO, NO₂ and O₃. Extreme values are detected with low O₃ and high NO₂ and NO concentrations between 100 and 150 m a.g.l. O₃ minimum levels (5^th percentile) of 5 ppbv coincident with NO₂ maximum levels (95^th percentile) of 40 ppbv occur around 200 m a.g.l. The peaks aloft are linked to pollution plumes originating from Fairbanks power plants such as documented with the flight of February 20.