Preprints
https://doi.org/10.5194/egusphere-2025-2167
https://doi.org/10.5194/egusphere-2025-2167
17 Jul 2025
 | 17 Jul 2025

Characterization of the UV radiometric calibration for the TROPOMI operational ozone profile retrieval algorithm

Serena Di Pede, Erwin Loots, Emiel van der Plas, Maarten Sneep, Edward van Amelrooy, Mirna van Hoek, Mark ter Linden, Antje Ludewig, Arno Keppens, and J. Pepijn Veefkind

Abstract. The European Space Agency (ESA) Sentinel-5 Precursor (S5P) is a low Earth orbit polar satellite carrying the single payload instrument TROPOspheric Monitoring Instrument (TROPOMI). Since its launch on 13 October 2017, the S5P mission has been acquiring almost 7 years of nadir ozone profile data, retrieved from the UV spectral bands 1–2 (270–330 nm). The retrieval algorithm of the ozone profile can be strongly affected by systematic effects in the measured radiance, and absolute calibration of the input spectra is necessary. In this study, we characterize the TROPOMI bands 1–2 radiometric bias in comparison with simulations obtained with the Determining Instrument Specifications and Analysing Methods for Atmospheric Retrieval (DISAMAR) radiative transfer model. To account for these systematic effects, a radiometric correction (soft-calibration) is applied to the input measurements, which results in the reduction of the spectral reflectance fit residuals of 20–30 %, improved precision of the integrated total and tropospheric ozone columns of 10–15 % and a reduction of along-track orbit artifacts. Together with the analysis of the in-flight calibration measurements, the soft-calibration correction spectra provide also useful insights for the improvement of the instrument radiometric calibration. Therefore, bands 1–2 measurements have been reprocessed specifically for this study, with improvements regarding the detector straylight and background signal correction algorithms, to investigate the impact of the updates into the TROPOMI bands 1–2 radiometric bias. The new soft-calibration correction spectra, obtained with the reprocessed bands 1–2 measurements, show significantly reduced magnitude (around 15–20 %, especially in band 1) and also less across-track position and spectral/temporal biases. The new soft-calibration will be part of ESA’s next official ozone profile algorithm version 2.9.0, coordinated with L1b update to processor version 3.0.0, and used for the second TROPOMI mission reprocessing.

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Journal article(s) based on this preprint

17 Mar 2026
Characterization and improvements of the UV radiometric calibration for the TROPOMI operational ozone profile retrieval algorithm
Serena Di Pede, Erwin Loots, Antje Ludewig, Emiel van der Plas, Edward van Amelrooy, Mirna van Hoek, Maarten Sneep, Mark ter Linden, Arno Keppens, and J. Pepijn Veefkind
Atmos. Meas. Tech., 19, 1875–1899, https://doi.org/10.5194/amt-19-1875-2026,https://doi.org/10.5194/amt-19-1875-2026, 2026
Short summary
Serena Di Pede, Erwin Loots, Emiel van der Plas, Maarten Sneep, Edward van Amelrooy, Mirna van Hoek, Mark ter Linden, Antje Ludewig, Arno Keppens, and J. Pepijn Veefkind

Interactive discussion

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2025-2167', Juseon Bak, 19 Jul 2025
    • AC1: 'Reply on RC1', Serena Di Pede, 07 Nov 2025
  • RC2: 'Comment on egusphere-2025-2167', Glen Jaross, 07 Aug 2025
    • AC2: 'Reply on RC2', Serena Di Pede, 07 Nov 2025

Interactive discussion

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2025-2167', Juseon Bak, 19 Jul 2025
    • AC1: 'Reply on RC1', Serena Di Pede, 07 Nov 2025
  • RC2: 'Comment on egusphere-2025-2167', Glen Jaross, 07 Aug 2025
    • AC2: 'Reply on RC2', Serena Di Pede, 07 Nov 2025

Peer review completion

AR – Author's response | RR – Referee report | ED – Editor decision | EF – Editorial file upload
AR by Serena Di Pede on behalf of the Authors (07 Nov 2025)  Author's response   Author's tracked changes   Manuscript 
ED: Referee Nomination & Report Request started (10 Nov 2025) by Mark Weber
RR by Juseon Bak (21 Nov 2025)
RR by Glen Jaross (25 Nov 2025)
ED: Reconsider after major revisions (01 Dec 2025) by Mark Weber
AR by Serena Di Pede on behalf of the Authors (27 Jan 2026)  Author's response   Author's tracked changes   Manuscript 
ED: Referee Nomination & Report Request started (28 Jan 2026) by Mark Weber
RR by Glen Jaross (03 Feb 2026)
ED: Publish subject to technical corrections (16 Feb 2026) by Mark Weber
AR by Serena Di Pede on behalf of the Authors (24 Feb 2026)  Author's response   Manuscript 

Journal article(s) based on this preprint

17 Mar 2026
Characterization and improvements of the UV radiometric calibration for the TROPOMI operational ozone profile retrieval algorithm
Serena Di Pede, Erwin Loots, Antje Ludewig, Emiel van der Plas, Edward van Amelrooy, Mirna van Hoek, Maarten Sneep, Mark ter Linden, Arno Keppens, and J. Pepijn Veefkind
Atmos. Meas. Tech., 19, 1875–1899, https://doi.org/10.5194/amt-19-1875-2026,https://doi.org/10.5194/amt-19-1875-2026, 2026
Short summary
Serena Di Pede, Erwin Loots, Emiel van der Plas, Maarten Sneep, Edward van Amelrooy, Mirna van Hoek, Mark ter Linden, Antje Ludewig, Arno Keppens, and J. Pepijn Veefkind
Serena Di Pede, Erwin Loots, Emiel van der Plas, Maarten Sneep, Edward van Amelrooy, Mirna van Hoek, Mark ter Linden, Antje Ludewig, Arno Keppens, and J. Pepijn Veefkind

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Short summary
The Sentinel-5P is a satellite operated by the European Space Agency, carrying the TROPOspheric Monitoring Instrument (TROPOMI). This mission also produces atmospheric ozone profile data using measurements in the ultra-violet spectrum. Absolute spectra calibration is necessary to produce high quality ozone profile data. Soft-calibration is a technique used to obtain accurate input spectra for ozone profile retrievals. The new soft-calibration shows reduced size and less temporal/spectral bias.
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