Preprints
https://doi.org/10.5194/egusphere-2025-2042
https://doi.org/10.5194/egusphere-2025-2042
11 Aug 2025
 | 11 Aug 2025
Status: this preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).

Measurement report: Molecular characterization of organic aerosol in coastal environments using offline FIGAERO-I-CIMS

Yuping Chen, Lingling Xu, Xiaolong Fan, Ziyi Lin, Chen Yang, Gaojie Chen, Ronghua Zheng, Youwei Hong, Mengren Li, Yanru Zhang, and Jinsheng Chen

Abstract. Organic aerosol (OA), as a key component of particulate matter, exerts significant impacts on public health and the environment. However, understanding of molecular characterization of OA under diverse environments remains limited. This study employed offline FIGAERO-I-CIMS (Filter Inlet for Gases and Aerosols coupled with iodide-adduct Chemical Ionization Mass Spectrometry) to analyze the molecular composition of OA in PM2.5 samples collected from a coastal city (urban and seaside sites) in Southeast China during spring 2024. A total of 737 and 768 CHOX compounds were identified at the urban and seaside sites, respectively. CHO compounds dominated in signal intensity (>70 %) at both sites, while CHON were more abundant at the urban site and S-containing compounds at the seaside site. The weighted effective oxygen numbers (urban 0.82, seaside 0.85) indicated higher oxidation levels in coastal compounds. Seaside CHOX exhibited lower unsaturation, reduced aromaticity, and higher oxidation states. Categorization showed that urban OA was more influenced by aromatic compounds, whereas seaside OA contained higher proportions of aged aliphatic compounds. Two distinct pollution episodes were selected to investigate CHOX evolution. Case 1 (local accumulation) showed enhanced CHON signals through NO3·-initiated nighttime oxidation that promoted Aliphatic Nitrates formation, whereas Case 2 (marine air masses) showed increased proportions of Aliphatic-like O-rich CHOX compounds (28 % to 39 %) via aqueous-phase processing probably under high humidity. These findings advance our understanding of OA molecular characteristics and chemical evolution under different environmental conditions.

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Yuping Chen, Lingling Xu, Xiaolong Fan, Ziyi Lin, Chen Yang, Gaojie Chen, Ronghua Zheng, Youwei Hong, Mengren Li, Yanru Zhang, and Jinsheng Chen

Status: open (until 22 Sep 2025)

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  • RC1: 'Comment on egusphere-2025-2042', Anonymous Referee #1, 26 Aug 2025 reply
  • RC2: 'Comment on egusphere-2025-2042', Anonymous Referee #2, 29 Aug 2025 reply
Yuping Chen, Lingling Xu, Xiaolong Fan, Ziyi Lin, Chen Yang, Gaojie Chen, Ronghua Zheng, Youwei Hong, Mengren Li, Yanru Zhang, and Jinsheng Chen

Data sets

Dataset for Molecular characterization of organic aerosol.xlsx Yuping Chen https://doi.org/10.6084/m9.figshare.28956629

Yuping Chen, Lingling Xu, Xiaolong Fan, Ziyi Lin, Chen Yang, Gaojie Chen, Ronghua Zheng, Youwei Hong, Mengren Li, Yanru Zhang, and Jinsheng Chen

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Short summary
This study investigates the molecular characteristics and chemical evolution of organic aerosol (OA) in contrasting urban and seaside environments by offline Chemical Ionization Mass Spectrometry. Urban OA was enriched in aromatic species, while seaside OA featured aliphatic and highly oxidized compounds. Marine-influenced humid air masses, combined with active photochemical conditions, promoted aqueous-phase OA formation, leading to higher oxidation states, particularly at the seaside site.
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