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Preprints
https://doi.org/10.5194/egusphere-2024-3512
https://doi.org/10.5194/egusphere-2024-3512
07 Feb 2025
 | 07 Feb 2025
Status: this preprint is open for discussion and under review for Geoscientific Model Development (GMD).

PALACE v1.0: Paranal Airglow Line And Continuum Emission model

Stefan Noll, Carsten Schmidt, Patrick Hannawald, Wolfgang Kausch, and Stefan Kimeswenger

Abstract. Below about 2.3 µm, the nighttime emission of the Earth's atmosphere is dominated by non-thermal radiation. Excluding aurorae, the emission is caused by chemical reaction chains which are driven by the daytime photolysis and photoionisation of constituents of the middle and upper atmosphere by hard ultraviolet photons from the Sun. As this airglow can even outshine scattered moonlight in the near-infrared regime, the understanding of the Earth's night-sky brightness requires good knowledge of the complex airglow emission spectrum and its variability. However, airglow modelling is very challenging as it would require atomic and molecular parameters, rate coefficients for chemical reactions, and knowledge of the complex dynamics at the emission heights with a level of detail that is difficult to achieve. In part, even the chemical reaction pathways remain unclear. Hence, the comprehensive characterisation of airglow emission requires large data sets of empirical data. For fixed locations, this can be best achieved by archived spectra of large astronomical telescopes with a wide wavelength coverage, high spectral resolving power, and good temporal sampling. Using 10 years of data from the X-shooter echelle spectrograph in the wavelength range from 0.3 to 2.5 µm and additional data from the Ultraviolet and Visual Echelle Spectrograph at the Very Large Telescope at Cerro Paranal in Chile, we have succeeded to build a comprehensive spectroscopic airglow model for this low-latitude site under consideration of theoretical data from the HITRAN database for molecules and from different sources for atoms. The Paranal Airglow Line And Continuum Emission (PALACE) model comprises 9 chemical species, 26,541 emission lines, and 3 unresolved continuum components. Moreover, there are climatologies of relative intensity, solar cycle effect, and residual variability with respect to local time and day of year for 23 variability classes. Spectra can be calculated with a stand-alone code for different conditions, also including optional atmospheric absorption and scattering. In comparison to the observed X-shooter spectra, PALACE shows convincing agreement and is significantly better than the previous, widely used airglow model for Cerro Paranal.

Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this preprint. The responsibility to include appropriate place names lies with the authors.
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Non-thermal emission from chemical reactions in the Earth's middle und upper atmosphere strongly...
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