Measurement report: Greenhouse gas profiles and age of air from the 2021 HEMERA-TWIN balloon launch

Abstract. Within the HEMERA balloon infrastructure project, a stratospheric balloon carrying a multi-instrument payload to a maximum altitude of 31.2 km was launched on 12th August 2021. Aboard the openly constructed TWIN gondola, several types of instruments were used for simultaneous air sampling and in-flight measurements to characterize climate relevant trace gases in the stratosphere and in the troposphere, and to compare and evaluate different instrumental approaches and sampling techniques. For observations of the main greenhouse gases carbon dioxide (CO₂), methane (CH₄), nitrous oxide (N₂O) and sulfur hexafluoride (SF₆), sampling with AirCores, flask sampling and in-flight spectrometry were deployed. Overall, results from different methods agree well. While better precision is achieved for the post-flight measurements of AirCores and flask sampling, in-situ spectrometry provides a higher degree of detail on the vertical structure of the CH₄ profile. Age of air was derived from mixing ratios of CO₂ and SF₆. As seen in previous studies, higher values were obtained from SF₆ than from CO₂. Correcting for chemical losses, maximum values of 4.4–5.1 years were derived from SF₆ mixing ratios at altitudes above 20 km compared to 4.2–5.0 years from CO₂ mixing ratios. The resulting dataset should be well suited for multi-tracer approaches to derive age of air, in particular in combination with a large suite of halocarbons measured from flask samples and one more AirCore which are reported by a companion publication.