Preprints
https://doi.org/10.5194/egusphere-2024-2752
https://doi.org/10.5194/egusphere-2024-2752
18 Sep 2024
 | 18 Sep 2024
Status: this preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).

Advances in OH reactivity instruments for airborne field measurements

Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli

Abstract. Hydroxyl radical OH reactivity, which is the inverse lifetime of the OH radical, provides information on the burden of air pollutants, since almost all air pollutants react with OH. OH reactivity measurements from field experiments can help to identify gaps in the measurement of individual reactants and serve as a proxy for the potential formation of secondary pollutants, including ozone and particles. However, OH reactivity is not regularly measured specifically on airborne platforms due to the technical complexity of the instruments and/or the need for careful instrumental characterisation to apply accurate correction factors to account for secondary chemistry in the instruments. The method used in this work, based on the time-resolved measurement of OH radicals produced by laser flash photolysis in a flow tube, does not require corrections as secondary chemistry in the instrument is negligible for typical atmospheric conditions. However, the detection of OH radicals by laser-induced fluorescence is challenging. In this work, an OH reactivity instrument has been further developed specifically for airborne measurements. The laser system used to detect the OH radicals has been simplified compared to previous setups, thereby significantly reducing the need for user interaction. The improved sensitivity allows measurements to be made with high time resolution on the order of seconds with a measurements precision of 0.3 s−1. The OH reactivity measurements were validated by using a propane gas standard, which allowed the determination of the reaction rate constant of the OH reaction with propane. The values are in excellent agreement with literature recommendations within a range of 4 to 8 %. Deviations are well within the combined uncertainties. The accuracy of the OH reactivity measurements is mainly limited by the determination of the instrumental zero, which has a typical maximum uncertainty of 0.5 s−1. The high sensitivity of the improved instrument facilitates the data acquisition on board an aircraft as demonstrated by its deployment during the AEROMMA campaign in 2023.

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Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli

Status: open (until 24 Oct 2024)

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Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli
Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli

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Short summary
Significant improvements have been made to the instruments used to measure OH reactivity, which is equivalent to the sum of air pollutant concentrations. Accurate and precise measurements with a high time resolution have been achieved, allowing use on aircraft, as demonstrated during flights in the USA.