Preprints
https://doi.org/10.5194/egusphere-2023-2798
https://doi.org/10.5194/egusphere-2023-2798
23 Jan 2024
 | 23 Jan 2024

Analysis of secondary inorganic aerosols over the Greater Area of Athens using the EPISODE-CityChem source dispersion and photochemistry model

Stelios Myriokefalitakis, Matthias Karl, Kim Andreas Weiss, Dimitris Karagiannis, Eleni Athanasopoulou, Anastasia Kakouri, Aikaterini Bougiatioti, Eleni Liakakou, Iasonas Stavroulas, Georgios Papangelis, Georgios Grivas, Despina Paraskevopoulou, Orestis Speyer, Nikolaos Mihalopoulos, and Evangelos Gerasopoulos

Abstract. Secondary inorganic aerosols (SIA) are major components of fine particulate matter (PM2.5), having substantial implications for climate and air quality in an urban environment. In this study, a state-of-the-art thermodynamic model has been coupled to the source dispersion and photochemistry city-scale chemistry transport model EPISODE-CityChem, able to simulate pollutants on a horizontal resolution of 100 x 100 m2, to determine the equilibrium between the inorganic gas and aerosol phases over the Greater Area of Athens, Greece, for the year 2019. In agreement with in-situ observations, sulfate (SO42-) is calculated to have the highest annual mean surface concentration (2.15 ± 0.88 μg m-3) among SIA in the model domain, followed by ammonium (NH4+; 0.58 ± 0.14 μg m-3) and fine nitrate (NO3-; 0.24 ± 0.22 μg m-3). Simulations denote that NO3- formation strongly depends on the local nitrogen oxide emissions, along with the ambient temperature, the relative humidity, and the photochemical activity. Additionally, we show that anthropogenic combustion sources may have an important impact on the NO3- formation in an urban area. During the cold period, the combined effect of decreased temperature in the presence of non-sea salt potassium favors the partitioning of HNO3 in the aerosol phase in the model, raising the NO3- formation in the area. Overall, this work highlights the significance of atmospheric composition and the local meteorological conditions for the equilibrium distribution of nitrogen-containing semivolatile compounds and the acidity of inorganic aerosols, especially in urban areas where atmospheric trace elements from natural and anthropogenic sources coexist.

Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this preprint. The responsibility to include appropriate place names lies with the authors.
Stelios Myriokefalitakis, Matthias Karl, Kim Andreas Weiss, Dimitris Karagiannis, Eleni Athanasopoulou, Anastasia Kakouri, Aikaterini Bougiatioti, Eleni Liakakou, Iasonas Stavroulas, Georgios Papangelis, Georgios Grivas, Despina Paraskevopoulou, Orestis Speyer, Nikolaos Mihalopoulos, and Evangelos Gerasopoulos

Status: final response (author comments only)

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2023-2798', Anonymous Referee #2, 19 Feb 2024
    • AC1: 'Reply on RC1', Stylianos Myriokefalitakis, 29 Apr 2024
  • RC2: 'Comment on egusphere-2023-2798', Anonymous Referee #1, 30 Mar 2024
    • AC2: 'Reply on RC2', Stylianos Myriokefalitakis, 29 Apr 2024
Stelios Myriokefalitakis, Matthias Karl, Kim Andreas Weiss, Dimitris Karagiannis, Eleni Athanasopoulou, Anastasia Kakouri, Aikaterini Bougiatioti, Eleni Liakakou, Iasonas Stavroulas, Georgios Papangelis, Georgios Grivas, Despina Paraskevopoulou, Orestis Speyer, Nikolaos Mihalopoulos, and Evangelos Gerasopoulos
Stelios Myriokefalitakis, Matthias Karl, Kim Andreas Weiss, Dimitris Karagiannis, Eleni Athanasopoulou, Anastasia Kakouri, Aikaterini Bougiatioti, Eleni Liakakou, Iasonas Stavroulas, Georgios Papangelis, Georgios Grivas, Despina Paraskevopoulou, Orestis Speyer, Nikolaos Mihalopoulos, and Evangelos Gerasopoulos

Viewed

Total article views: 342 (including HTML, PDF, and XML)
HTML PDF XML Total BibTeX EndNote
259 66 17 342 9 9
  • HTML: 259
  • PDF: 66
  • XML: 17
  • Total: 342
  • BibTeX: 9
  • EndNote: 9
Views and downloads (calculated since 23 Jan 2024)
Cumulative views and downloads (calculated since 23 Jan 2024)

Viewed (geographical distribution)

Total article views: 338 (including HTML, PDF, and XML) Thereof 338 with geography defined and 0 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 
Latest update: 18 May 2024
Download
Short summary
A state-of-the-art thermodynamic model has been coupled to the source dispersion and photochemistry city-scale chemistry transport model EPISODE-CityChem to determine the equilibrium between the inorganic gas and aerosol phases over the Greater Area of Athens, Greece. Simulations denote that nitrate formation strongly depends on the local nitrogen oxide emissions, along with the ambient temperature, the relative humidity, the photochemical activity, and the presence of nonvolatile cations.