Preprints
https://doi.org/10.5194/egusphere-2022-1249
https://doi.org/10.5194/egusphere-2022-1249
12 Dec 2022
 | 12 Dec 2022

Methodological advances to improve repeatability of SOA generation in environmental chambers

Austin C. Flueckiger and Giuseppe A. Petrucci

Abstract. Most laboratory atmospheric chamber studies probing the chemical and physical properties of secondary organic aerosol (SOA) perform such experiments with mixing ratios of volatile organic compounds (VOCs) well-above atmospheric relevance (≳50 ppbv). When performing ozonolysis of biogenic VOCs at mixing ratios of atmospheric relevance (≲10 ppbv), repeatability of replicate experiments is hindered by the limitations of conventional VOC injection techniques. To overcome these limitations, two novel components (stop/flow and split valves) were embedded in a conventional VOC injection setup, thereby permitting the use of higher VOC volumes of injection to attain low VOC mixing ratios, and the delivery of the VOC to the environmental chamber as a short, discrete pulse for subsequent reaction. Implementation of these novel VOC injection components has resulted in improvements in variability between replicate chamber experiments of up to a factor of 7 with respect to particle number, mass, and size distributions at both high and low VOC mixing ratios (50 and 10 ppbv, respectively). These improvements permit extension of quantitative measurements of SOA formation to VOC mixing ratios at or near atmospheric levels, where new particle formation (NPF) and SOA mass loading are typically within experimental variability.

Austin C. Flueckiger and Giuseppe A. Petrucci

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2022-1249', Anonymous Referee #1, 20 Dec 2022
  • RC2: 'Comment on egusphere-2022-1249', Anonymous Referee #2, 04 Jan 2023

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2022-1249', Anonymous Referee #1, 20 Dec 2022
  • RC2: 'Comment on egusphere-2022-1249', Anonymous Referee #2, 04 Jan 2023
Austin C. Flueckiger and Giuseppe A. Petrucci
Austin C. Flueckiger and Giuseppe A. Petrucci

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Latest update: 21 Feb 2024
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Short summary
Laboratory chamber experiments are a mainstay of organic aerosol research. Much of what we know today about the chemical formation and aging of organic particles is derived from chamber studies. The repeatability of chamber measurements remains poor however, a limitation that will become more important as studies using atmospherically relevant reactant concentrations become more common. We report on two method innovations that greatly improve the inherent variability of chamber measurements.