Preprints
https://doi.org/10.5194/egusphere-2022-1056
https://doi.org/10.5194/egusphere-2022-1056
 
02 Nov 2022
02 Nov 2022
Status: this preprint is open for discussion.

Potential of TROPOMI for understanding spatio-temporal variations in surface NO2 and their dependencies upon land use over the Iberian Peninsula

Hervé Petetin1, Marc Guevara1, Steven Compernolle2, Dene Bowdalo1, Pierre-Antoine Bretonnière1, Santiago Enciso1, Oriol Jorba1, Franco Lopez1, Albert Soret1, and Carlos Pérez García-Pando1,3 Hervé Petetin et al.
  • 1Barcelona Supercomputing Center, Barcelona, Spain
  • 2Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Ringlaan 3, 1180 Uccle, Belgium
  • 3ICREA, Passeig Lluís Companys 23, 08010 Barcelona, Spain

Abstract. In orbit since late 2017, the Tropospheric Monitoring Instrument (TROPOMI) is offering new outstanding opportunities for better understanding the emission and fate of nitrogen dioxide (NO2) pollution in the troposphere. In this study, we provide a comprehensive analysis of the spatio-temporal variability of TROPOMI NO2 tropospheric columns (TrC-NO2) over the Iberian Peninsula during 2018–2021 (considering the TrC-NO2 PAL product recently developed using a single TROPOMI processor version, thus ensuring consistency over the time period). We complement our analysis with estimates of NOx anthropogenic and natural soil emissions. Closely related to cloud cover, the data availability of TROPOMI observations ranges from 30–45 % during April and November to 70–80 % during summertime, with strong variations between northern and southern Spain. Strongest TrC-NO2 hotspots are located over Madrid and Barcelona, while TrC-NO2 enhancements are also observed along international maritime routes close the strait of Gibraltar, and to a lesser extent along specific major highways. TROPOMI TrC-NO2 appear reasonably well correlated with collocated surface NO2 mixing ratios, with correlations around 0.7–0.8 depending on the averaging time.

We investigate the changes of weekly and monthly variability of TROPOMI TrC-NO2 depending on the urban cover fraction. Weekly profiles show a reduction of TrC-NO2 during the weekend ranging from -10 to -40 % from least to most urbanized areas, in reasonable agreement with surface NO2. In the largest agglomerations like Madrid or Barcelona, this weekend effect peaks not in the city center but in specific suburban areas/cities, suggesting a larger relative contribution of commuting to total NOx anthropogenic emissions. The TROPOMI TrC-NO2 monthly variability also strongly varies with the level of urbanisation, with monthly differences relative to annual mean ranging from -40 % in summer to +60 % in winter in the most urbanized areas, and from -10 to +20 % in the least urbanized areas. When focusing on agricultural areas, TROPOMI observations depict an enhancement in June–July that could come from natural soil NO emissions. Some specific analysis in Madrid show that the relatively sharp NO2 minimum used to occur in August (drop of road transport during holidays) has now evolved into a much broader minimum partly de-coupled from the observed local road traffic counting; this change started in 2018, thus before the COVID-19 outbreak.

All in all, our study illustrates the strong potential of TROPOMI TrC-NO2 observations for complementing the existing surface NO2 monitoring stations, especially in the poorly covered rural and maritime areas where NOx can play a key role, notably for the production of tropospheric O3.

Hervé Petetin et al.

Status: open (until 14 Dec 2022)

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Hervé Petetin et al.

Hervé Petetin et al.

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Short summary
This study analyses the potential of the TROPOMI space sensor for monitoring the variability of NO2 pollution over the Iberian Peninsula. A reduction of NO2 levels is observed during the weekend and in summer, especially over most urbanized areas, in agreement with surface observations. An enhancement of NO2 is found during summer with TROPOMI over croplands, potentially related to natural soil NO emissions, which illustrates the outstanding value of TROPOMI for complementing surface networks.