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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-6413</article-id>
<title-group>
<article-title>A Novel Approach Combining Mechanism and Machine Learning to Unravel Oxidant-Driven Formation Regimes of &amp;alpha;-Pinene-Derived Oxygenated Organic Molecules (OOMs)</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Tan</surname>
<given-names>Rui</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ni</surname>
<given-names>Xinshi</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wan</surname>
<given-names>Zichao</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Tian</surname>
<given-names>Xudong</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Shen</surname>
<given-names>Jiasi</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Xu</surname>
<given-names>Bingye</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Xu</surname>
<given-names>Da</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lu</surname>
<given-names>Sihua</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Li</surname>
<given-names>Xin</given-names>
<ext-link>https://orcid.org/0000-0003-2322-4069</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Guo</surname>
<given-names>Song</given-names>
<ext-link>https://orcid.org/0000-0002-9661-2313</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>State Key Laboratory of Regional Environment and Sustainability, International Joint Research Center for Atmospheric Research (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Nanjing University of Information Science &amp; Technology, Nanjing 210044, China</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Ecological and Environmental Monitoring Center of Zhejiang Province, Hangzhou 310012, China</addr-line>
</aff>
<pub-date pub-type="epub">
<day>30</day>
<month>10</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>26</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Rui Tan et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-6413/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-6413/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-6413/egusphere-2026-6413.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-6413/egusphere-2026-6413.pdf</self-uri>
<abstract>
<p>Monoterpene oxidation produces oxygenated organic molecules (OOMs) that act as secondary organic aerosol precursors, but the roles of ozone (O&lt;sub&gt;3&lt;/sub&gt;) and the hydroxyl radical (OH) in their ambient formation are hard to separate because the two oxidants co-vary. We fitted an ensemble of tree-based regression models to one month of online mass-spectrometric measurements at a coastal background site in eastern China and ranked the predictors of four OOM classes defined by hydrogen content (H14&amp;ndash;H20) using Shapley additive explanations. Within the fitted models, ozone accounts for 70.8&amp;ndash;79.4 % of the relative predictive importance and OH for 20.6&amp;ndash;29.2 %. The balance shifts along the series, the class retaining the hydrogen count of the parent monoterpene depending most strongly on ozone and the most saturated class most strongly on OH. The ozone response is not uniform: below about 62 ppb (62.0&amp;ndash;63.6 ppb across the four classes) the models extract little ozone signal, whereas above this level ozone becomes a strong positive predictor for all four classes. Three independent checks support this pattern (Appendix B). Both the weights and the transition level derive from a single campaign and are site-specific; the analysis can be repeated wherever these variables are measured.</p>
</abstract>
<counts><page-count count="26"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>National Key Research and Development Program of China</funding-source>
<award-id>2022YFC3701002</award-id>
<award-id>2022YFC3703502</award-id>
</award-group>
<award-group id="gs2">
<funding-source>National Natural Science Foundation of China</funding-source>
<award-id>22221004</award-id>
</award-group>
</funding-group>
</article-meta>
</front>
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