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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-6252</article-id>
<title-group>
<article-title>Seasonally decoupled dynamics of dissolved organic carbon and fluorescent dissolved organic matter in continental shelf waters</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Han</surname>
<given-names>Heejun</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Cho</surname>
<given-names>Hyung-Mi</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hwang</surname>
<given-names>Jeomshik</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lee</surname>
<given-names>Hanbyul</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kim</surname>
<given-names>Guebuem</given-names>
<ext-link>https://orcid.org/0000-0002-5119-0241</ext-link>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Marine Environmental Research Department, Korea Institute of Ocean Science and Technology (KIOST), Busan, 49111,   South Korea</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Ocean Sciences, Inha University, Incheon, 22212, South Korea</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Schoo of Earth and Environmental Sciences/Research Institute of Oceanography, Seoul National University, Seoul, 08826,  South Korea</addr-line>
</aff>
<pub-date pub-type="epub">
<day>10</day>
<month>11</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>18</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Heejun Han et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-6252/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-6252/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-6252/egusphere-2026-6252.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-6252/egusphere-2026-6252.pdf</self-uri>
<abstract>
<p>We investigated seasonal variations in dissolved organic carbon (DOC) and humic-like fluorescent dissolved organic matter (FDOM&lt;sub&gt;H&lt;/sub&gt;) in the Yellow Sea and East China Sea to better understand the factors shaping dissolved organic matter (DOM) dynamics in continental shelf waters. Multi-year observations revealed that DOC concentrations increased with Radium based water residence time, whereas FDOM&lt;sub&gt;H&lt;/sub&gt; showed no corresponding accumulation across seasons. This contrasting behavior was particularly evident during summer, when strong solar radiation may promote preferential degradation of photo-labile FDOM&lt;sub&gt;H&lt;/sub&gt;, while a relatively more photo-resistant DOC remains in shelf waters, indicating a seasonal decoupling between DOC and FDOM&lt;sub&gt;H&lt;/sub&gt;. The persistent increase in DOC with water residence time suggests that a fraction of DOC can accumulate in shelf waters despite ongoing degradation processes. Based on the observed relationship between DOC and water residence time, we estimated a net DOC accumulation flux of 1.1&amp;plusmn;0.2 Tg C yr&lt;sup&gt;-1&lt;/sup&gt;, comparable in magnitude to annual riverine DOC inputs in this region. Our findings highlight the contrasting dynamics of DOC and FDOM&lt;sub&gt;H&lt;/sub&gt; and suggest that prolonged water residence and selective DOM transformation may contribute to DOC persistence in continental shelf waters, potentially supporting the export of persistent DOC to the open ocean.</p>
</abstract>
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<funding-group>
<award-group id="gs1">
<funding-source>Korea Institute of Marine Science and Technology promotion</funding-source>
<award-id>RS-2023-00256174</award-id>
</award-group>
<award-group id="gs2">
<funding-source>Korea Institute of Ocean Science and Technology</funding-source>
<award-id>PEA0455</award-id>
</award-group>
<award-group id="gs3">
<funding-source>National Research Foundation of Korea</funding-source>
<award-id>RS-2023-00210846</award-id>
<award-id>RS-2026-25477176</award-id>
</award-group>
</funding-group>
</article-meta>
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