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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-5869</article-id>
<title-group>
<article-title>Mitigating the role of Pb loss on Maximum Depositional Age estimation using Chemical Abrasion-Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Donaghy</surname>
<given-names>Erin E.</given-names>
<ext-link>https://orcid.org/0009-0005-9002-1036</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Eddy</surname>
<given-names>Michael P.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ibañez-Mejia</surname>
<given-names>Mauricio</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Geoscience, University of Nevada, Las Vegas, 89154, United States of America</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, 47907, United  States of America</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Department of Geosciences, University of Arizona, Tucson, 85721, United States of America</addr-line>
</aff>
<pub-date pub-type="epub">
<day>20</day>
<month>10</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>14</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Erin E. Donaghy et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5869/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5869/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5869/egusphere-2026-5869.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5869/egusphere-2026-5869.pdf</self-uri>
<abstract>
<p>It is increasingly recognized that Pb loss in zircon of even Cenozoic age is pervasive and can lead to &lt;sup&gt;206&lt;/sup&gt;Pb/&lt;sup&gt;238&lt;/sup&gt;U and &lt;sup&gt;207&lt;/sup&gt;Pb/&lt;sup&gt;235&lt;/sup&gt;U dates that are younger than the mineral&amp;rsquo;s crystallization date. Therefore, applications of U-Pb geochronology that rely on identifying a sample&amp;rsquo;s youngest age component, like the determination of a detrital zircon sample&amp;rsquo;s maximum depositional age (MDA), can be compromised if Pb loss is not mitigated. Here, we test whether the use of bulk chemical abrasion (CA) prior to laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) detrital zircon U-Pb geochronology can eliminate Pb loss, specifically to improve low-n MDA estimation methods of Cenozoic zircon. We analyzed CA-treated and untreated aliquots of two Cenozoic sandstones from southern Alaska and found all untreated fractions have zircon with younger apparent &lt;sup&gt;206&lt;/sup&gt;Pb/&lt;sup&gt;238&lt;/sup&gt;U dates than treated zircon fractions. To assess whether this discrepancy is a result of Pb loss, the youngest zircon grains in all aliquots were extracted and dated using chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS). All chemically abraded date pairs agree within 2&amp;sigma; uncertainty, whereas untreated LA-ICP-MS analyses give &lt;sup&gt;206&lt;/sup&gt;Pb/&lt;sup&gt;238&lt;/sup&gt;U dates that are distinctly younger than their corresponding CA-ID-TIMS dates by 4.1&amp;ndash;15.9 %. We conclude the CA-LA-ICP-MS method provides an avenue to improve the accuracy of low-n MDA estimations and subsequent geological interpretations.</p>
</abstract>
<counts><page-count count="14"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>National Science Foundation</funding-source>
<award-id>EAR 2342541</award-id>
<award-id>EAR 2151277</award-id>
</award-group>
</funding-group>
</article-meta>
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