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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-5836</article-id>
<title-group>
<article-title>Development of a lightweight broadband cavity-enhanced spectrometer system for simultaneous monitoring of HONO and NO&lt;sub&gt;2&lt;/sub&gt;</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Li</surname>
<given-names>Yilan</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Womack</surname>
<given-names>Caroline C.</given-names>
<ext-link>https://orcid.org/0000-0002-7101-9054</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schafer</surname>
<given-names>Nell B.</given-names>
<ext-link>https://orcid.org/0009-0000-2287-3775</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Chai</surname>
<given-names>Jiajue</given-names>
<ext-link>https://orcid.org/0000-0003-2818-0579</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Chemistry, State University of New York, College of Environmental Science and Forestry, Syracuse, NY</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Department of Chemistry, University of Colorado, Boulder, CO 80309, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>03</day>
<month>11</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>25</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Yilan Li et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5836/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5836/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5836/egusphere-2026-5836.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5836/egusphere-2026-5836.pdf</self-uri>
<abstract>
<p>Nitrous acid (HONO) is an important source of hydroxyl radicals in the troposphere, but its measurement remains challenging because of its low atmospheric abundance and rapid temporal variability. In this work, we developed a compact broadband cavity-enhanced absorption spectrometer (BBCEAS) for simultaneous measurements of HONO and NO&lt;sub&gt;2&lt;/sub&gt; in the near-UV spectral region. The instrument uses a high-reflectivity optical cavity, with a measured mirror reflectivity of 0.99986 at 368 nm, and a spectral acquisition time of 0.15 s. Laboratory characterization demonstrated stable and sensitive measurements of both species. The instrument achieved 1&amp;sigma; precisions of 193 pptv for HONO and 584 pptv for NO&lt;sub&gt;2&lt;/sub&gt; at 1 s time resolution, improving to 30 pptv and 76 pptv, respectively, at a 60 s averaging time. Intercomparison measurements showed excellent agreement with reference analyzers, with nearly unit regression slopes for both HONO and NO&lt;sub&gt;2&lt;/sub&gt;. Controlled humidity experiments showed no systematic dependence of the retrieved concentrations on water vapour over the investigated range, indicating robust performance under varying humidity conditions. In addition, a 24 h ambient deployment in Syracuse, New York, USA, demonstrated the practical applicability of the instrument for continuous measurements of atmospheric HONO and NO&lt;sub&gt;2&lt;/sub&gt;. The instrument provided high-temporal-resolution measurements of HONO and NO&lt;sub&gt;2&lt;/sub&gt; and enabled continuous measurements of HONO at 10s of pptv levels. The combination of high sensitivity, rapid acquisition, compact design, and stable performance provides potential for continuous monitoring across diverse environments and for integration with mobile and airborne platforms.</p>
</abstract>
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<funding-group>
<award-group id="gs1">
<funding-source>National Science Foundation</funding-source>
<award-id>2331252</award-id>
</award-group>
<award-group id="gs2">
<funding-source>National Science Foundation</funding-source>
<award-id>2305090</award-id>
</award-group>
</funding-group>
</article-meta>
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