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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-5384</article-id>
<title-group>
<article-title>Direct Measurements of N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; Reactivity in Salt Lake City Suggest the Aerosol Nitrate Effect Suppresses Additional PM&lt;sub&gt;2.5&lt;/sub&gt; Accumulation</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Christie</surname>
<given-names>James A.</given-names>
<ext-link>https://orcid.org/0000-0003-3010-4962</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Severud</surname>
<given-names>Theo</given-names>
<ext-link>https://orcid.org/0009-0001-9404-6864</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Forshee</surname>
<given-names>Logan</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Selimovic</surname>
<given-names>Vanessa</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wang</surname>
<given-names>Siyuan</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Roy</surname>
<given-names>Shatabdi</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lawson</surname>
<given-names>Holly P.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Garcia</surname>
<given-names>Maria A.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hallar</surname>
<given-names>A. Gannet</given-names>
<ext-link>https://orcid.org/0000-0001-9972-0056</ext-link>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Humble</surname>
<given-names>Haley</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lin</surname>
<given-names>John C.</given-names>
<ext-link>https://orcid.org/0000-0003-2794-184X</ext-link>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zuidema</surname>
<given-names>Paquita</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pratt</surname>
<given-names>Kerri A.</given-names>
<ext-link>https://orcid.org/0000-0003-4707-2290</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gaston</surname>
<given-names>Cassandra J.</given-names>
<ext-link>https://orcid.org/0000-0003-1383-8585</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Atmospheric Science, Rosenstiel School for Marine, Atmospheric, &amp; Earth Sciences, University of Miami, Fl 33149, USA</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Department of Atmospheric Sciences, University of Utah, Salt Lake City, UT 84112, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Department of Earth &amp; Environmental Sciences, University of Michigan, Ann Abor, MI 48109, USA</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>present affiliation: Geophysical Institute, University of Alaska, Fairbanks, AK 99775, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>09</day>
<month>09</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>25</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 James A. Christie et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5384/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5384/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5384/egusphere-2026-5384.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5384/egusphere-2026-5384.pdf</self-uri>
<abstract>
<p>Salt Lake City (SLC) frequently experiences severe wintertime pollution due to the accumulation of fine particulate matter, which is dominated by ammonium nitrate (AN) during atmospheric inversion events. Recent measurements in SLC have shown that heterogeneous reactions between gaseous dinitrogen pentoxide (N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;) and ambient aerosol drives AN accumulation in SLC. However, information is lacking on the ambient aerosol sources present, and how efficiently these particles react with N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; to form AN. As such, we deployed an ambient aerosol flow tube coupled to a chemical ionization mass spectrometer and particle sizing instrumentation at the University of Utah in winter to probe the reactive uptake of N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; (&amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt; &lt;/sub&gt;that leads to AN formation. Aerosol particle composition was measured from offline filter collections and ion chromatography to determine how different particle sources react with N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;. Under inversion conditions, we measured suppressed values of &amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; (median &amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; = 0.03 &amp;plusmn; 0.04) that decreased to as low as 0.001 when high AN was measured, suggesting that the nitrate effect suppresses &amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; by ~ 0.02 per night. Under clean conditions, we observed elevated values of &amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; (median &amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; = 0.06 &amp;plusmn; 0.05) due to efficient heterogeneous reactions with mineral dust, ammonium sulfate, and road salt aerosol with no notable decrease in &amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; throughout clean periods. Using a 1-dimensional chemical box model, we find that aerosol nitrate accumulation is limited when &amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; is less than 0.01 throughout the evening. These results suggest that the most important influence on &amp;gamma;N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; in wintertime SLC is the nitrate effect.</p>
</abstract>
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<funding-group>
<award-group id="gs1">
<funding-source>National Oceanic and Atmospheric Administration</funding-source>
<award-id>NA20OAR4310298</award-id>
<award-id>NA20OAR4310299</award-id>
</award-group>
</funding-group>
</article-meta>
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