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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-5307</article-id>
<title-group>
<article-title>An incoherent broadband cavity-enhanced absorption spectrometer for simultaneous NO&lt;sub&gt;3&lt;/sub&gt; and N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; measurements, integrated into a NO&lt;sub&gt;y&lt;/sub&gt; instrument suite: characterization and first field deployment</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dewald</surname>
<given-names>Patrick</given-names>
<ext-link>https://orcid.org/0000-0001-6922-3016</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Harb</surname>
<given-names>Sergio</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Picquet-Varrault</surname>
<given-names>Bénédicte</given-names>
<ext-link>https://orcid.org/0000-0001-5158-8703</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Cazaunau</surname>
<given-names>Mathieu</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Feingesicht</surname>
<given-names>Maxime</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Beltran</surname>
<given-names>Lucas</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Michoud</surname>
<given-names>Vincent</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Landsheere</surname>
<given-names>Xavier</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pangui</surname>
<given-names>Edouard</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bergé</surname>
<given-names>Antonin</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Cantrell</surname>
<given-names>Christopher</given-names>
<ext-link>https://orcid.org/0000-0002-3844-1560</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Cirtog</surname>
<given-names>Manuela</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Université Paris Est Créteil and Université de Paris Cité, CNRS, LISA, F-94010 Créteil, France</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institut National de l’Environnement industriel et des Risques (INERIS), F-60550 Verneuil en Halatte, France</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Université Paris Cité and Université Paris Est Créteil, CNRS, LISA, F-75013 Paris, France</addr-line>
</aff>
<pub-date pub-type="epub">
<day>09</day>
<month>09</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>40</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Patrick Dewald et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5307/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5307/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5307/egusphere-2026-5307.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5307/egusphere-2026-5307.pdf</self-uri>
<abstract>
<p>Reactive nitrogen species (NO&lt;sub&gt;y&lt;/sub&gt;) are involved in the formation of secondary pollutants, thus following their interconversions is crucial for understanding their impact on air quality. While nitric oxide (NO) and nitrogen dioxide (NO&lt;sub&gt;2&lt;/sub&gt;), are important contributors to total NO&lt;sub&gt;y&lt;/sub&gt;, further constituents such as the nitrate radical (NO&lt;sub&gt;3&lt;/sub&gt;) and dinitrogen pentoxide (N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;), formed from NO&lt;sub&gt;2 &lt;/sub&gt;oxidation, are key intermediates in nocturnal oxidation processes. Even though NO&lt;sub&gt;3&lt;/sub&gt; and N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; affect the NO&lt;sub&gt;y&lt;/sub&gt; budget in the following day, their role is poorly constrained in isolated measurements. We present the &amp;ldquo;NOyBOx&amp;rdquo;, a new instrumental framework combining measurements of NO, NO&lt;sub&gt;2&lt;/sub&gt; and NO&lt;sub&gt;y&lt;/sub&gt; from commercial analyzers with a custom-built incoherent broadband cavity-enhanced absorption spectrometer (IBBCEAS) that measures NO&lt;sub&gt;3&lt;/sub&gt; directly and N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; via a thermal dissociation inlet (TDI) and channel differencing. We describe the design of the IBB-CEAS subsystem, characterize the TDI, cavity optics, transmission losses, and, using a synthetic spectra simulation approach, the bias of ambient NO&lt;sub&gt;2&lt;/sub&gt; and water vapor on our concentration retrieval procedure. Under optimal laboratory conditions we find a limit of detection (LOD) of 1.5 and 2.2 pptv (1&amp;sigma; Allan deviation, 15 s) for NO&lt;sub&gt;3&lt;/sub&gt; and N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;, respectively. Under field conditions, interference by water vapor and NO&lt;sub&gt;2&lt;/sub&gt; worsens these LODs to 3.1 pptv with a total measurement uncertainty (TMU) of 12 % for NO&lt;sub&gt;3&lt;/sub&gt;, and to 4.4 pptv with a mean TMU of 21 % for N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;. Exemplary results from its first deployment during a field campaign in a temperate forest atop a 40 m tall tower are discussed.</p>
</abstract>
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<funding-group>
<award-group id="gs1">
<funding-source>Agence Nationale de la Recherche</funding-source>
<award-id>ANR-17-MPGA-0002</award-id>
</award-group>
<award-group id="gs2">
<funding-source>Centre National de la Recherche Scientifique</funding-source>
<award-id>LEFE</award-id>
</award-group>
<award-group id="gs3">
<funding-source>HORIZON EUROPE Marie Sklodowska-Curie Actions</funding-source>
<award-id>101206921 (NOCTEM)</award-id>
</award-group>
<award-group id="gs4">
<funding-source>Agence de l&apos;Environnement et de la Maîtrise de l&apos;Energie</funding-source>
<award-id>ADEME</award-id>
</award-group>
</funding-group>
</article-meta>
</front>
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