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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-5207</article-id>
<title-group>
<article-title>Reconciling online and offline source apportionment of brown carbon absorption in wintertime Seoul</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kim</surname>
<given-names>Hwajin</given-names>
<ext-link>https://orcid.org/0000-0001-6138-6443</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Chen</surname>
<given-names>Yanfang</given-names>
<ext-link>https://orcid.org/0009-0005-1129-4774</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Environmental Health Sciences, Graduate School of Public Health, Seoul National University, Seoul 08826, Republic of Korea</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institute of Health and Environment, Seoul National University, Seoul 08826, Republic of Korea</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>now at: Paul Scherrer Institute (PSI), Villigen, Switzerland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>11</day>
<month>09</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>37</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Hwajin Kim</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5207/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5207/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5207/egusphere-2026-5207.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5207/egusphere-2026-5207.pdf</self-uri>
<abstract>
<p>Brown carbon (BrC) is a leading uncertainty in aerosol radiative forcing, and the source-resolved mass absorption coefficients (MAC) used in climate models come from both real-time (online) and filter-based (offline) measurements. Both are widely trusted, yet have rarely been applied to the same aerosol and compared source by source, leaving the assumption that they are interchangeable untested. Here we ask whether online and offline source apportionment yield the same sources of BrC absorption for wintertime urban aerosol. We combined a seven-wavelength aethalometer with high-resolution aerosol mass spectrometry (online, whole particle) and 24 h PM2.5 filter UV&amp;ndash;Vis of water extracts (offline), attributing bulk absorption to positive-matrix-factorization factors by regression on each platform. The two platforms agreed on the bulk attribution (winter BrC carried by secondary and biomass-burning OA) and on consistency with worldwide observations, but inverted the source ranking: online, biomass burning and less oxidized secondary organic aerosol dominated while more oxidized OA (MO-OOA) was negligible (MAC 0.07 m&amp;sup2; g⁻&amp;sup1;); offline, MO-OOA dominated (0.88 m&amp;sup2; g⁻&amp;sup1;). This reversal reflects how the sample is measured, not an atmospheric change: water-soluble selection and a likely shift of MO-OOA toward reduced-nitrogen chromophores during offline preparation, while bulk composition and factor time series are preserved. The source inferred for BrC absorption is therefore strongly dependent on method and integration time, a critical caution for source-resolved BrC parameterizations that treat online and offline datasets as interchangeable.</p>
</abstract>
<counts><page-count count="37"/></counts>
</article-meta>
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