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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="methods-article" specific-use="SMUR" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-5050</article-id>
<title-group>
<article-title>Technical note: Cavity ring-down spectroscopy is a precise and accurate method for measuring &lt;sup&gt;15&lt;/sup&gt;N-NO&lt;sub&gt;3&lt;/sub&gt;&amp;ndash; in soil extracts from &lt;sup&gt;15&lt;/sup&gt;N tracer experiments</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hashmi</surname>
<given-names>Wasi</given-names>
<ext-link>https://orcid.org/0009-0003-2095-0337</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Marushchak</surname>
<given-names>Maija E.</given-names>
<ext-link>https://orcid.org/0000-0002-2308-5049</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Martinez</surname>
<given-names>Paula Martinez-Risco</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gil</surname>
<given-names>Jenie</given-names>
<ext-link>https://orcid.org/0000-0001-6176-6542</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kohl</surname>
<given-names>Lukas</given-names>
<ext-link>https://orcid.org/0000-0002-5902-9444</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>University of Eastern Finland, Department of Environmental and Biological Sciences, 70210 Kuopio, Finland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>01</day>
<month>09</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>8</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Wasi Hashmi et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5050/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5050/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5050/egusphere-2026-5050.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-5050/egusphere-2026-5050.pdf</self-uri>
<abstract>
<p>Cavity ring-down spectroscopy (CRDS) provides a low-cost alternative to isotope ratio mass spectrometry (IRMS) for the analysis of &lt;sup&gt;15&lt;/sup&gt;N-NO&lt;sub&gt;3&lt;/sub&gt;⁻ in nitrogen cycle assays, but its performance has not been tested systematically for highly enriched samples. Here we report results from 271 parallel analyses of &lt;sup&gt;15&lt;/sup&gt;N-NO&lt;sub&gt;3&lt;/sub&gt;⁻ in soil extracts after chemical conversion to N&lt;sub&gt;2&lt;/sub&gt;O, including low (0.36&amp;ndash;1.45 at%) and high labelled samples (0.46&amp;ndash;8.49 at%). We demonstrate that CRDS measurements deliver comparable accuracy and precision to continuous-flow Gas Bench-IRMS analysis (slope: 0.982 and 0.972, RMSE: 0.0018 and 0.254 at% for low- and high-labelled samples, respectively), thereby offering a robust and affordable alternative for classic &lt;sup&gt;15&lt;/sup&gt;N-NO&lt;sub&gt;3&lt;/sub&gt;⁻ analysis.</p>
</abstract>
<counts><page-count count="8"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>Research Council of Finland</funding-source>
<award-id>349503</award-id>
<award-id>353858</award-id>
<award-id>354501</award-id>
<award-id>362253</award-id>
</award-group>
<award-group id="gs2">
<funding-source>Atmosphere and Climate Competence Center</funding-source>
<award-id>357905</award-id>
</award-group>
</funding-group>
</article-meta>
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