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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-4590</article-id>
<title-group>
<article-title>Impact of urban-industrial air pollution on chemically reactive greenhouse gases is highly sensitive to organic nitrate formation</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wilson</surname>
<given-names>Calum Patrick</given-names>
<ext-link>https://orcid.org/0009-0000-1066-4976</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Prather</surname>
<given-names>Michael John</given-names>
<ext-link>https://orcid.org/0000-0002-9442-8109</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Earth System Science, University of California, Irvine, Irvine, 92697, United States of America</addr-line>
</aff>
<pub-date pub-type="epub">
<day>21</day>
<month>08</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>16</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Calum Patrick Wilson</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-4590/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-4590/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-4590/egusphere-2026-4590.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-4590/egusphere-2026-4590.pdf</self-uri>
<abstract>
<p>We compute net tropospheric ozone production (P-O&lt;sub&gt;3&lt;/sub&gt;) and methane oxidation (L-CH&lt;sub&gt;4&lt;/sub&gt;) caused by 45 days of South Korean emissions using a chemistry-transport model (CTM) and a hybrid modelling system (HMS). The CTM has global 1&amp;deg; x 1&amp;deg; resolution; the HMS has detailed chemical mechanisms and a refined regional grid (0.1&amp;deg; x 0.1&amp;deg;), but simplified, staged transport. The emissions cause +22.1 Gmol P-O&lt;sub&gt;3&lt;/sub&gt; and +2.0 Gmol L-CH&lt;sub&gt;4&lt;/sub&gt; in the CTM &lt;em&gt;vs&lt;/em&gt;. +31.2 Gmol P-O&lt;sub&gt;3&lt;/sub&gt; and +4.3 Gmol L-CH&lt;sub&gt;4&lt;/sub&gt; in the HMS. Differences are attributed to lower volatile organic compound (VOC) reactivity in the CTM, thus decreased organic nitrate export to the free troposphere. Time-integrated O&lt;sub&gt;3&lt;/sub&gt; mass perturbations (𝛿O&lt;sub&gt;3&lt;/sub&gt;) are similar in both models and constitute a globally-averaged +0.03 DU summertime O&lt;sub&gt;3&lt;/sub&gt; enhancement. Due to contrasting L-CH&lt;sub&gt;4&lt;/sub&gt;, the net steady-state effective radiative forcing sustained by the emissions is +0.49 mW m&lt;sup&gt;-2&lt;/sup&gt; in the CTM and -0.25 mW m&lt;sup&gt;-2&lt;/sup&gt; in the HMS.</p>
</abstract>
<counts><page-count count="16"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>National Aeronautics and Space Administration</funding-source>
<award-id>80NSSC21K1454</award-id>
</award-group>
<award-group id="gs2">
<funding-source>National Science Foundation</funding-source>
<award-id>AGS-2135749</award-id>
</award-group>
</funding-group>
</article-meta>
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