Recent experimental and theoretical work has highlighted missing pathways in the oxidation of aromatic compounds, with consequences for the formation of highly oxygenated products relevant to secondary organic aerosol (SOA) formation. In this study we develop an updated, quasi-explicit oxidation mechanism for benzene based on Master Chemical Mechanism (MCM) v3.3.1, extended to represent key multi-generation chemistry. Quantum chemical calculations are used to derive the formation and evolution of geminal-diol bicyclic peroxy radicals and to parameterize the subsequent molecular rearrangements. The mechanism further incorporates autoxidation sequences previously developed for peroxy and alkoxy radicals, successive OH additions and cyclic epoxides formation. This approach enables a more mechanistic description of aromatic oxidation leading to highly oxygenated, low-volatility products. The mechanism is evaluated using box-model simulations against a set of chamber experiments conducted under various conditions. Simulated aerosol concentrations agree well with observations and emphasize the dominant contribution of the newly implemented pathways. The quasi-explicit mechanism is subsequently reduced using the GENerator of reduced Organic Aerosol mechanisms (GENOA), resulting in a semi-explicit mechanism reduced to 1 % of its original number of species while reproducing SOA mass with a mean error of 3.9 % relative to the quasi-explicit scheme. Using the validated reduced mechanism, zero-dimensional simulations under contrasted atmospheric conditions are conducted to estimate the SOA compounds that are formed in the early stages of oxidation and those that dominate the system at later stages.