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<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-2487</article-id>
<title-group>
<article-title>A small-footprint Cavity Ring-Down Spectroscopy instrument for in-situ measurements of NO&lt;sub&gt;3&lt;/sub&gt; and N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Türk</surname>
<given-names>Gunther N. T. E.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Andersen</surname>
<given-names>Simone T.</given-names>
<ext-link>https://orcid.org/0000-0002-6657-4862</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dewald</surname>
<given-names>Patrick</given-names>
<ext-link>https://orcid.org/0000-0001-6922-3016</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schuladen</surname>
<given-names>Jan</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lelieveld</surname>
<given-names>Jos</given-names>
<ext-link>https://orcid.org/0000-0001-6307-3846</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Crowley</surname>
<given-names>John N.</given-names>
<ext-link>https://orcid.org/0000-0001-8669-0230</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Atmospheric Chemistry Department, Max Planck Institute for Chemistry, 55128 Mainz, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>08</day>
<month>05</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>28</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Gunther N. T. E. Türk et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-2487/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-2487/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-2487/egusphere-2026-2487.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-2487/egusphere-2026-2487.pdf</self-uri>
<abstract>
<p>We present a new, small-footprint instrument for point measurements of NO₃ and N₂O₅. Both molecules play an important role in nocturnal atmospheric chemistry, impacting the NOₓ-budget and the oxidation of biogenic volatile organic compounds. NO₃ and N₂O₅ are often present at concentrations of a few parts per trillion by volume (pptv) and their measurements in remote locations requires instrumentation that is easily transported and lightweight, but maintains high sensitivity and accuracy. We have constructed a relatively compact and light instrument for Cavity Ring-Down Spectroscopy (CRDS) with the dimensions (width &amp;times; depth &amp;times; height) of 55 &amp;times; 55 &amp;times; 150 cm and a weight of 50 kg that uses two independent cavities to quantify the mixing ratio of NO₃ using an inlet at room temperature and the sum of NO₃ + N₂O₅ via a thermal dissociation inlet. Under laboratory conditions, limits of detection (1&amp;sigma; Allan deviation at 1 s integration) for the NO₃ and (NO₃ + N₂O₅) channel are &amp;lt; 1 pptv and &amp;lt; 2 pptv, respectively. This improves to about 0.1 pptv and 0.2 pptv for 3-minute integration. The total measurement uncertainty for NO₃ is 9.8 % and &amp;ge; 11.5 % for N₂O₅, depending on the NO₃-to-N₂O₅ ratio.&lt;/p&gt;
&lt;p&gt;In this publication, we present design details of the instrument, discuss its performance in a controlled environment as well as during a field campaign. Additionally, we present measurements of transmission losses for NO₃ across different filter types and methods to reduce filter reactivity and allow reusability after a cleaning procedure.</p>
</abstract>
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