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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2026-1470</article-id>
<title-group>
<article-title>Advancing Halocarbon Radiative Efficiency Estimates by coupling radiative transfer and quantum chemical calculations: impact of updated spectroscopic parameters and low-frequency contributions</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Alvarado-Jimenez</surname>
<given-names>Daniela</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Tasinato</surname>
<given-names>Nicola</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Buizza</surname>
<given-names>Roberto</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Shine</surname>
<given-names>Keith P.</given-names>
<ext-link>https://orcid.org/0000-0003-2672-9978</ext-link>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Scuola Normale Superiore, Piazza dei Cavalieri 7, Pisa, Italy</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>IUSS Scuola Universitaria Superiore Pavia, Piazza della Vittoria 15, Pavia, Italy</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Sant’Anna School of Advanced Studies, Piazza Martiri della Libertá 33, Pisa, Italy</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Department of Meteorology, University of Reading,Reading, RG6 7ET, United Kingdom</addr-line>
</aff>
<pub-date pub-type="epub">
<day>16</day>
<month>04</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>20</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Daniela Alvarado-Jimenez et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-1470/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-1470/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2026-1470/egusphere-2026-1470.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2026-1470/egusphere-2026-1470.pdf</self-uri>
<abstract>
<p>We update a fast method for calculating the global mean radiative efficiency (RE) for weak absorbers (known as the Pinnock Curve). It is then employed to evaluate improved REs, for 30 halocarbons focusing particularly on the low-wavenumber (&amp;lt;500 cm&lt;sup&gt;-1&lt;/sup&gt;) contributions where laboratory measurements of absorption cross-sections are scarce. The Pinnock Curve is updated using spectral line parameters from the HITRAN2020 database and the MT_CKD_4.3 water vapor continuum formulation. Halocarbon REs are evaluated by coupling this update with infrared absorption cross section spectra evaluated by means of a quantum chemical protocol featuring a non-empirical inclusion of anharmonic effects in both transition frequencies and intensities and accounting for conformer distributions. Recent revisions to the MT_CKD water vapor continuum coefficients decrease atmospheric opacity, producing a small increase in RE, which is counteracted by updates to line-by-line spectroscopic parameters in HITRAN2020. These compensatory effects result in a small increase in halocarbon REs, with an average rise of ~0.3 %. Analysis of the low-wavenumber region shows that for the targeted compounds it contributes no more than 5 mW m&lt;sup&gt;-2 &lt;/sup&gt;ppb&lt;sup&gt;-1&lt;/sup&gt;. On average, it amounts to 0.9 % of the total RE, but reaches about 3 % for HFC-152a and HFC-161. Despite this modest magnitude, accurate treatment of this spectral range is essential, as its impact is molecule-dependent and even small contributions can influence climate metrics. For seven of the 30 gases considered here, the low frequency contribution to RE is more than 10 times greater than that calculated in earlier work.</p>
</abstract>
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<funding-group>
<award-group id="gs1">
<funding-source>Natural Environment Research Council</funding-source>
<award-id>NE/X004198/1</award-id>
</award-group>
<award-group id="gs2">
<funding-source>European Commission</funding-source>
<award-id>Not applicable</award-id>
</award-group>
</funding-group>
</article-meta>
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