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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2025-6095</article-id>
<title-group>
<article-title>Mechanisms of air-sea CO&lt;sub&gt;2&lt;/sub&gt; exchange in the central Baltic Sea</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dong</surname>
<given-names>Yuanxu</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Marandino</surname>
<given-names>Christa A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dobashi</surname>
<given-names>Ryo</given-names>
<ext-link>https://orcid.org/0000-0002-2265-2611</ext-link>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ho</surname>
<given-names>David</given-names>
<ext-link>https://orcid.org/0000-0002-0944-6952</ext-link>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rehder</surname>
<given-names>Gregor</given-names>
<ext-link>https://orcid.org/0000-0002-0597-9989</ext-link>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bittig</surname>
<given-names>Henry C.</given-names>
<ext-link>https://orcid.org/0000-0002-8621-3095</ext-link>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Karnatz</surname>
<given-names>Josefine</given-names>
<ext-link>https://orcid.org/0009-0009-2649-6546</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sabbaghzadeh</surname>
<given-names>Bita</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Czerski</surname>
<given-names>Helen</given-names>
<ext-link>https://orcid.org/0000-0002-9181-0580</ext-link>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Engel</surname>
<given-names>Anja</given-names>
<ext-link>https://orcid.org/0000-0002-1042-1955</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Marine Biogeochemistry Research Division, GEOMAR Helmholtz Centre for Ocean Research Kiel, Kiel, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institute of Environmental Physics, Heidelberg University, Heidelberg, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Department of Oceanography, University of Hawaiʻi at Mānoa, Honolulu, Hawaii, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Leibniz Institute for Baltic Sea Research Warnemünde, Rostock, Germany</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Department of Mechanical Engineering, University College London, London, UK</addr-line>
</aff>
<pub-date pub-type="epub">
<day>19</day>
<month>01</month>
<year>2026</year>
</pub-date>
<volume>2026</volume>
<fpage>1</fpage>
<lpage>44</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2026 Yuanxu Dong et al.</copyright-statement>
<copyright-year>2026</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2025-6095/">This article is available from https://egusphere.copernicus.org/preprints/2026/egusphere-2025-6095/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2026/egusphere-2025-6095/egusphere-2025-6095.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2026/egusphere-2025-6095/egusphere-2025-6095.pdf</self-uri>
<abstract>
<p>Air-sea gas exchange regulates the cycling of climate-relevant gases such as carbon dioxide (CO&lt;sub&gt;2&lt;/sub&gt;), yet large uncertainties remain in its quantification. The gas transfer velocity (&lt;em&gt;K&lt;/em&gt;), a key parameter for estimating CO&lt;sub&gt;2&lt;/sub&gt; flux, is usually expressed as a function of wind speed (&lt;em&gt;U&lt;/em&gt;&lt;sub&gt;10N&lt;/sub&gt;). This approach overlooks the role of fetch and surfactants, which can substantially affect &lt;em&gt;K&lt;/em&gt;. However, no field study has systematically quantified their combined effects under fetch-limited and surfactant-abundant ocean conditions. To fill this research gap, we conducted air-sea gas exchange studies during a cruise in the central Baltic Sea, a system with high surfactant levels and a short fetch. We report independent determinations of &lt;em&gt;K&lt;/em&gt; using eddy covariance (EC) and dual-tracer techniques, together with direct measurements of natural surfactants and modelled wave parameters. Both methods yield consistent results; however, EC-based CO&lt;sub&gt;2&lt;/sub&gt; transfer velocities are on average 33 % lower than those reported in the open ocean in previous EC studies. Sea-state-dependent parameterisations indicate that limited fetch reduces &lt;em&gt;K&lt;/em&gt; by 8 %, while elevated surfactant concentrations may have contributed to the additional 25 % reduction. We developed an updated parameterization that includes wind stress, sea state, and surfactants. When applied to climatological forcing, it yields a 40 % stronger seasonal cycle of CO&lt;sub&gt;2&lt;/sub&gt; flux in the Baltic Sea than obtained with the conventional &lt;em&gt;U&lt;/em&gt;&lt;sub&gt;10N&lt;/sub&gt;-based parameterization. These findings highlight the need to move beyond &lt;em&gt;U&lt;/em&gt;&lt;sub&gt;10N&lt;/sub&gt; in the parameterization of &lt;em&gt;K&lt;/em&gt; and estimation of regional fluxes, especially when evaluating the potential of marine carbon dioxide removal (mCDR) in coastal seas.</p>
</abstract>
<counts><page-count count="44"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>Alexander von Humboldt-Stiftung</funding-source>
<award-id>Humboldt Research Fellowship for Postdocs</award-id>
</award-group>
</funding-group>
</article-meta>
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