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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2025-6012</article-id>
<title-group>
<article-title>Modelling the Life&amp;ndash;Cycle Impacts of Air Pollution on Tropospheric Ozone and Methane</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wilson</surname>
<given-names>Calum P.</given-names>
<ext-link>https://orcid.org/0009-0000-1066-4976</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Prather</surname>
<given-names>Michael J.</given-names>
<ext-link>https://orcid.org/0000-0002-9442-8109</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Earth System Science, University of California, Irvine, Irvine CA, 92697, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>05</day>
<month>12</month>
<year>2025</year>
</pub-date>
<volume>2025</volume>
<fpage>1</fpage>
<lpage>40</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2025 Calum P. Wilson</copyright-statement>
<copyright-year>2025</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-6012/">This article is available from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-6012/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-6012/egusphere-2025-6012.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-6012/egusphere-2025-6012.pdf</self-uri>
<abstract>
<p>We calculate the global change in the production of tropospheric ozone (O&lt;sub&gt;3&lt;/sub&gt;) and loss of methane (CH&lt;sub&gt;4&lt;/sub&gt;) caused by 45 days of summertime South Korean anthropogenic emissions during the Korea-US Air Quality (KORUS-AQ) mission. Our modelling system consists of three stages: the boundary layer-residual layer (BL-RL) stage processes the emissions, photochemistry, deposition, aerosol reactivity, and transport over terrestrial South Korea at 0.1&amp;deg; x 0.1&amp;deg; with hourly resolution. The plume (PL) stage continues to integrate the chemistry of air masses from the BL-RL stage as they are transported offshore, simulating offshore pollution plumes observed by aircraft. After three days of chemical aging in non-diluting plumes, the pollution remnants are dispersed (DP stage) into the background atmosphere and integrated until the pollution disappears. Net O&lt;sub&gt;3&lt;/sub&gt; production is diagnosed in each stage using the integrated ozone change and our calculated perturbation lifetimes. In total, these 45 days of South Korean emissions create an excess CH&lt;sub&gt;4&lt;/sub&gt; sink of 4.3 Gmol and a net O&lt;sub&gt;3&lt;/sub&gt; source of 31.2 Gmol. Scaling these values to annual global emissions suggests around 10 % of CH&lt;sub&gt;4&lt;/sub&gt; loss and 30 % of net O&lt;sub&gt;3&lt;/sub&gt; production is attributable to anthropogenic air pollution, but our Korean summertime case may exaggerate the proportions. Reducing plume aging time to 2 days increases these terms by about 10 %, and immediate dispersion (no plume aging) more than doubles them. Our model supports the typical result that rapid dispersion of pollution, &lt;em&gt;e.g. &lt;/em&gt;through coarse resolution, overestimates its impact on tropospheric O&lt;sub&gt;3&lt;/sub&gt; and CH&lt;sub&gt;4&lt;/sub&gt;.</p>
</abstract>
<counts><page-count count="40"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>National Aeronautics and Space Administration</funding-source>
<award-id>80NSSC21K1454</award-id>
</award-group>
<award-group id="gs2">
<funding-source>National Science Foundation</funding-source>
<award-id>AGS-2135749</award-id>
</award-group>
</funding-group>
</article-meta>
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