<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "https://jats.nlm.nih.gov/nlm-dtd/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" specific-use="SMUR" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1867-8610</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2025-5422</article-id>
<title-group>
<article-title>TROPOMI/WFMD v2.0: Improved retrievals of XCH&lt;sub&gt;4&lt;/sub&gt; and XCO with XGBoost-based quality filtering</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schneising</surname>
<given-names>Oliver</given-names>
<ext-link>https://orcid.org/0000-0003-1725-8246</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bovensmann</surname>
<given-names>Heinrich</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Buchwitz</surname>
<given-names>Michael</given-names>
<ext-link>https://orcid.org/0000-0001-7616-1837</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Buschmann</surname>
<given-names>Matthias</given-names>
<ext-link>https://orcid.org/0000-0001-5077-9524</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Deutscher</surname>
<given-names>Nicholas M.</given-names>
<ext-link>https://orcid.org/0000-0002-2906-2577</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Griffith</surname>
<given-names>David W. T.</given-names>
<ext-link>https://orcid.org/0000-0002-7986-1924</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hachmeister</surname>
<given-names>Jonas</given-names>
<ext-link>https://orcid.org/0000-0001-5700-4502</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hase</surname>
<given-names>Frank</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Iraci</surname>
<given-names>Laura T.</given-names>
<ext-link>https://orcid.org/0000-0002-2859-5259</ext-link>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kivi</surname>
<given-names>Rigel</given-names>
<ext-link>https://orcid.org/0000-0001-8828-2759</ext-link>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Morino</surname>
<given-names>Isamu</given-names>
<ext-link>https://orcid.org/0000-0003-2720-1569</ext-link>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ohyama</surname>
<given-names>Hirofumi</given-names>
<ext-link>https://orcid.org/0000-0003-2109-9874</ext-link>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Petri</surname>
<given-names>Christof</given-names>
<ext-link>https://orcid.org/0000-0002-7010-5532</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Reuter</surname>
<given-names>Maximilian</given-names>
<ext-link>https://orcid.org/0000-0001-9141-3895</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Robinson</surname>
<given-names>John</given-names>
</name>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Roehl</surname>
<given-names>Coleen</given-names>
</name>
<xref ref-type="aff" rid="aff8">
<sup>8</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sha</surname>
<given-names>Mahesh Kumar</given-names>
<ext-link>https://orcid.org/0000-0003-1440-1529</ext-link>
</name>
<xref ref-type="aff" rid="aff9">
<sup>9</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Shiomi</surname>
<given-names>Kei</given-names>
<ext-link>https://orcid.org/0000-0002-1206-8614</ext-link>
</name>
<xref ref-type="aff" rid="aff10">
<sup>10</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Strong</surname>
<given-names>Kimberly</given-names>
</name>
<xref ref-type="aff" rid="aff11">
<sup>11</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sussmann</surname>
<given-names>Ralf</given-names>
<ext-link>https://orcid.org/0000-0002-1970-7538</ext-link>
</name>
<xref ref-type="aff" rid="aff12">
<sup>12</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Té</surname>
<given-names>Yao</given-names>
<ext-link>https://orcid.org/0000-0001-6405-8074</ext-link>
</name>
<xref ref-type="aff" rid="aff13">
<sup>13</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Velazco</surname>
<given-names>Voltaire A.</given-names>
<ext-link>https://orcid.org/0000-0002-1376-438X</ext-link>
</name>
<xref ref-type="aff" rid="aff14">
<sup>14</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Vrekoussis</surname>
<given-names>Mihalis</given-names>
<ext-link>https://orcid.org/0000-0001-8292-8352</ext-link>
</name>
<xref ref-type="aff" rid="aff15">
<sup>15</sup>
</xref>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff16">
<sup>16</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wang</surname>
<given-names>Wei</given-names>
</name>
<xref ref-type="aff" rid="aff17">
<sup>17</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Warneke</surname>
<given-names>Thorsten</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Weidmann</surname>
<given-names>Damien</given-names>
<ext-link>https://orcid.org/0000-0002-0178-7904</ext-link>
</name>
<xref ref-type="aff" rid="aff18">
<sup>18</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wunch</surname>
<given-names>Debra</given-names>
<ext-link>https://orcid.org/0000-0002-4924-0377</ext-link>
</name>
<xref ref-type="aff" rid="aff11">
<sup>11</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhou</surname>
<given-names>Minqiang</given-names>
<ext-link>https://orcid.org/0000-0003-3427-5873</ext-link>
</name>
<xref ref-type="aff" rid="aff19">
<sup>19</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bösch</surname>
<given-names>Hartmut</given-names>
<ext-link>https://orcid.org/0000-0003-3944-9879</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute of Environmental Physics (IUP), University of Bremen, Bremen, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Environmental Futures, School of Science, University of Wollongong, Wollongong, NSW, Australia</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Karlsruhe Institute of Technology (KIT), IMKASF, Karlsruhe, Germany</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Earth Science Division, NASA Ames Research Center, Moffett Field, CA, USA</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Space and Earth Observation Centre, Finnish Meteorological Institute, Sodankylä, Finland</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>Satellite Remote Sensing Section and Satellite Observation Center, Earth System Division, National Institute for Environmental Studies (NIES), Tsukuba, Ibaraki, Japan</addr-line>
</aff>
<aff id="aff7">
<label>7</label>
<addr-line>Earth Sciences New Zealand, Omakau, New Zealand</addr-line>
</aff>
<aff id="aff8">
<label>8</label>
<addr-line>California Institute of Technology, Pasadena, CA, USA</addr-line>
</aff>
<aff id="aff9">
<label>9</label>
<addr-line>Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium</addr-line>
</aff>
<aff id="aff10">
<label>10</label>
<addr-line>Earth Observation Research Center (EORC), Japan Aerospace Exploration Agency (JAXA), Tsukuba, Ibaraki, Japan</addr-line>
</aff>
<aff id="aff11">
<label>11</label>
<addr-line>Department of Physics, University of Toronto, Toronto, Ontario, Canada</addr-line>
</aff>
<aff id="aff12">
<label>12</label>
<addr-line>Karlsruhe Institute of Technology (KIT), IMKIFU, Garmisch-Partenkirchen, Germany</addr-line>
</aff>
<aff id="aff13">
<label>13</label>
<addr-line>Sorbonne Université, CNRS, MONARIS, UMR8233, Paris, France</addr-line>
</aff>
<aff id="aff14">
<label>14</label>
<addr-line>Deutscher Wetterdienst (DWD), Meteorological Observatory Hohenpeissenberg, Hohenpeissenberg, Germany</addr-line>
</aff>
<aff id="aff15">
<label>15</label>
<addr-line>Climate and Atmosphere Research Centre (CARE-C), The Cyprus Institute, Nicosia, Cyprus</addr-line>
</aff>
<aff id="aff16">
<label>16</label>
<addr-line>Center of Marine Environmental Sciences (MARUM), University of Bremen, Bremen, Germany</addr-line>
</aff>
<aff id="aff17">
<label>17</label>
<addr-line>Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei, China</addr-line>
</aff>
<aff id="aff18">
<label>18</label>
<addr-line>STFC Rutherford Appleton Laboratory, Space Science and Technology Department, Harwell Campus, Didcot, UK</addr-line>
</aff>
<aff id="aff19">
<label>19</label>
<addr-line>State Key Laboratory of Atmospheric Environment and Extreme Meteorology, Institute of Atmospheric Physics, Chinese  Academy of Sciences, Beijing, China</addr-line>
</aff>
<pub-date pub-type="epub">
<day>13</day>
<month>11</month>
<year>2025</year>
</pub-date>
<volume>2025</volume>
<fpage>1</fpage>
<lpage>39</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2025 Oliver Schneising et al.</copyright-statement>
<copyright-year>2025</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-5422/">This article is available from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-5422/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-5422/egusphere-2025-5422.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-5422/egusphere-2025-5422.pdf</self-uri>
<abstract>
<p>The TROPOspheric Monitoring Instrument (TROPOMI) on board the Sentinel-5 Precursor satellite provides daily global observations of atmospheric methane (CH&lt;sub&gt;4&lt;/sub&gt;) and carbon monoxide (CO) at relatively high spatial resolution. The dense spatial and temporal coverage is achieved by the instrument&amp;rsquo;s wide swath, which permits detailed mapping of the worldwide distribution of these important atmospheric constituents. The adaptation and optimisation of the Weighting Function Modified Differential Optical Absorption Spectroscopy (WFMD) algorithm for the simultaneous retrieval of the column-averaged dry-air mole fractions XCH&lt;sub&gt;4&lt;/sub&gt; and XCO from TROPOMI&amp;rsquo;s shortwave infrared (SWIR) radiance measurements has proven to be a valuable complement and alternative to the operational TROPOMI products.&lt;/p&gt;
&lt;p&gt;The latest release of the TROPOMI/WFMD product (version 2.0) includes several improvements expanding its suitability for a wider range of scientific applications. Data yield at mid and high latitudes has increased, accompanied by improved accuracy and precision according to the validation with the ground-based Total Carbon Column Observing Network (TCCON). These advancements are primarily due to more refined quality filtering that has been accomplished by replacing the previous Random Forest Classifier with the more efficient and potentially higher performing Extreme Gradient Boosting (XGBoost) algorithm in conjunction with improved training data incorporating an updated cloud product from the Visible Infrared Imaging Radiometer Suite (VIIRS) and the TROPOMI Aerosol Index. This enhanced training data set enables more reliable identification of cloudy scenes and mitigates issues related to specific aerosol events over bright surfaces. Importantly, as with previous product versions, the actual quality classification does not depend on the real-time availability of these external data products, which are only required during the training phase.</p>
</abstract>
<counts><page-count count="39"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>European Space Agency</funding-source>
<award-id>4000126450/19/I-NB</award-id>
<award-id>4000142730/23/I-NS</award-id>
</award-group>
<award-group id="gs2">
<funding-source>Bundesministerium für Forschung, Technologie und Raumfahrt</funding-source>
<award-id>01 LK2103A</award-id>
</award-group>
</funding-group>
</article-meta>
</front>
<body/>
<back>
</back>
</article>