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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2025-429</article-id>
<title-group>
<article-title>Can atmospheric chemistry deposition schemes reliably simulate stomatal ozone flux across global land covers and climates?</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Emmerichs</surname>
<given-names>Tamara</given-names>
<ext-link>https://orcid.org/0000-0002-0165-9574</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff11">
<sup>11</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Al Mamun</surname>
<given-names>Abdulla</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Emberson</surname>
<given-names>Lisa</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Mao</surname>
<given-names>Huiting</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhang</surname>
<given-names>Leiming</given-names>
<ext-link>https://orcid.org/0000-0001-5437-5412</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ran</surname>
<given-names>Limei</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Betancourt</surname>
<given-names>Clara</given-names>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wong</surname>
<given-names>Anthony</given-names>
<ext-link>https://orcid.org/0000-0001-6386-3063</ext-link>
</name>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Koren</surname>
<given-names>Gerbrand</given-names>
<ext-link>https://orcid.org/0000-0002-2275-0713</ext-link>
</name>
<xref ref-type="aff" rid="aff8">
<sup>8</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gerosa</surname>
<given-names>Giacomo</given-names>
<ext-link>https://orcid.org/0000-0002-5352-3222</ext-link>
</name>
<xref ref-type="aff" rid="aff9">
<sup>9</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Huang</surname>
<given-names>Min</given-names>
</name>
<xref ref-type="aff" rid="aff10">
<sup>10</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Guaita</surname>
<given-names>Pierluigi</given-names>
<ext-link>https://orcid.org/0000-0002-5970-8113</ext-link>
</name>
<xref ref-type="aff" rid="aff9">
<sup>9</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute of Energy and Climate Systems, Troposphere (ICE-3), Forschungszentrum Jülich,  Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Air Quality Research Division, Science and Technology Branch, Environment and Climate  Change Canada, Toronto, Ontario M3H 5T4, Canada</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Environment &amp; Geography Department, University of York, York, UK</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Department of Chemistry, State University of New York College of Environmental Science  and Forestry, Syracuse, NY, 13210, USA</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Resource Assessment Branch, USDA-NRCS-SSRA-RIAD</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>AXA Konzern AG, Cologne, Germany</addr-line>
</aff>
<aff id="aff7">
<label>7</label>
<addr-line>Centre for Global Change Science, Massachusetts Institute of Technology, Cambridge, MA, United States of America</addr-line>
</aff>
<aff id="aff8">
<label>8</label>
<addr-line>Copernicus Institute of Sustainable Development, Utrecht University, Utrecht, the Netherlands</addr-line>
</aff>
<aff id="aff9">
<label>9</label>
<addr-line>Dep.t of Mathematics and Physics, Catholic University of the Sacred Heart, Brescia, Italy</addr-line>
</aff>
<aff id="aff10">
<label>10</label>
<addr-line>Earth System Science Interdisciplinary Center, University of Maryland, College Park, MD,  USA</addr-line>
</aff>
<aff id="aff11">
<label>11</label>
<addr-line>now at: Max-Planck-Institute for Meteorology, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>14</day>
<month>02</month>
<year>2025</year>
</pub-date>
<volume>2025</volume>
<fpage>1</fpage>
<lpage>53</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2025 Tamara Emmerichs et al.</copyright-statement>
<copyright-year>2025</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-429/">This article is available from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-429/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-429/egusphere-2025-429.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-429/egusphere-2025-429.pdf</self-uri>
<abstract>
<p>Over the past few decades, ozone risk assessments for vegetation have been developed based on stomatal O&lt;sub&gt;3&lt;/sub&gt; flux since this metric is more biologically meaningful than the traditional concentration-based approaches. However, uncertainty remains in the ability to simulate stomatal O&lt;sub&gt;3&lt;/sub&gt; fluxes accurately. Here, we investigate stomatal O&lt;sub&gt;3&lt;/sub&gt; fluxes simulated by six common air pollution deposition models across various land cover types worldwide. The Tropospheric Ozone Assessment Report (TOAR) database, a large collection of measurements worldwide, provides hourly O&lt;sub&gt;3&lt;/sub&gt; concentration and meteorological data which are used to drive the models at 9 sites. The models estimated summertime O&lt;sub&gt;3&lt;/sub&gt; deposition velocities of between 0.5&amp;ndash;0.8 cm s&lt;sup&gt;-1&lt;/sup&gt;, mostly in agreement with the literature. Simulations of canopy conductance (G&lt;sub&gt;st&lt;/sub&gt;) showed differences between models that varied by land cover type with correlation coefficients of 0.75, 0.80 and 0.85 for forests, crops and grasslands. The model differences were determined by especially soil moisture and VPD depending upon the model constructs. Finally, the range of POD&lt;sub&gt;y&lt;/sub&gt; simulations at each site across models was most in agreement for crops (3 to 11 mmol O&lt;sub&gt;3&lt;/sub&gt; m&lt;sup&gt;-2&lt;/sup&gt;) &amp;lt; forests (10 to 23 mmol O&lt;sub&gt;3&lt;/sub&gt; m&lt;sup&gt;-2&lt;/sup&gt;) &amp;lt; grasslands (24 to 26 mmol O&lt;sub&gt;3&lt;/sub&gt; m&lt;sup&gt;-2&lt;/sup&gt;). Nevertheless, ensemble model median response estimates gave results consistent with the literature in terms of those sites where O&lt;sub&gt;3&lt;/sub&gt; damage is most likely to occur. Overall, this study is an important first step in developing and evaluating tools for broad-scale assessment of O&lt;sub&gt;3&lt;/sub&gt; impact on vegetation within the framework of TOAR phase II.</p>
</abstract>
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