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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2025-4005</article-id>
<title-group>
<article-title>Elevated Anthropogenic Contributions to Trace Elements in Marine Aerosols Compared to Coastal Qingdao in Eastern China</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Qi</surname>
<given-names>Yuxuan</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Li</surname>
<given-names>Wenshuai</given-names>
<ext-link>https://orcid.org/0000-0002-1322-2994</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Qu</surname>
<given-names>Wen</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhang</surname>
<given-names>Haizhou</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhu</surname>
<given-names>Wenqing</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Shi</surname>
<given-names>Jinhui</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhang</surname>
<given-names>Daizhou</given-names>
<ext-link>https://orcid.org/0000-0002-1448-2325</ext-link>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhang</surname>
<given-names>Yanjing</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sheng</surname>
<given-names>Lifang</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wang</surname>
<given-names>Wencai</given-names>
<ext-link>https://orcid.org/0000-0002-9587-6982</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhao</surname>
<given-names>Yunhui</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ma</surname>
<given-names>Yuanyuan</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ren</surname>
<given-names>Danyang</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wu</surname>
<given-names>Guanru</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wang</surname>
<given-names>Xinfeng</given-names>
<ext-link>https://orcid.org/0000-0003-0911-7312</ext-link>
</name>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Yao</surname>
<given-names>Xiaohong</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhou</surname>
<given-names>Yang</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>State Key Laboratory of Physical Oceanography, Ocean University of China, Qingdao, 266100, China</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>College of Oceanic and Atmospheric Sciences, Ocean University of China, Qingdao, 266100, China</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Key Laboratory of Marine Environment and Ecology, Ministry of Education, Ocean University of China, Qingdao, 266100,  China</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Laboratory for Marine Ecology and Environmental Science, Qingdao National Laboratory for Marine Science and  Technology, Qingdao, 266237, China</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>North Sea Bureau of Ministry of Natural Resources of the People’s Republic of China, Qingdao, 266061, China</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>Faculty of Environmental and Symbiotic Sciences, Prefectural University of Kumamoto, 862-8502, Japan</addr-line>
</aff>
<aff id="aff7">
<label>7</label>
<addr-line>Environment Research Institute, Shandong University, Qingdao, 266237, China</addr-line>
</aff>
<pub-date pub-type="epub">
<day>09</day>
<month>09</month>
<year>2025</year>
</pub-date>
<volume>2025</volume>
<fpage>1</fpage>
<lpage>26</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2025 Yuxuan Qi et al.</copyright-statement>
<copyright-year>2025</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-4005/">This article is available from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-4005/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-4005/egusphere-2025-4005.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-4005/egusphere-2025-4005.pdf</self-uri>
<abstract>
<p>Trace elements (TEs) in aerosols over offshore eastern China originate from both terrestrial and marine emissions. However, their variations with source regions remain poorly understood. During spring and summer 2018, PM&lt;sub&gt;2.5&lt;/sub&gt; samples were collected at Qingdao, a coastal city in eastern China, and adjacent Bohai and Yellow Seas. TEs were quantified and analyzed by source region, followed by source apportionment. In spring, TE concentrations were significantly higher over land. Crustal dust contributed 39.2&amp;ndash;77.8 % of Fe, Mn, Cr and Ni; while waste and industrial emissions contributed 29.4&amp;ndash;70.1 % of Cu, Zn and Pb. Westerly winds conveyed anthropogenic TEs offshore, with coal combustion contributing 25.9&amp;ndash;61.4 % to As, Cd, Pb, Zn and Cr, and oil combustion contributing 58.6&amp;ndash;84.4 % to V and Ni in marine aerosols, indicating efficient long-range pollutant transport. In summer, dust influence declined. Biomass burning contributed 38.2&amp;ndash;46.3 % of Zn, Cd, Pb and Cr, while vehicular emissions dominated As and Cu (41.7&amp;ndash;57.3 %) at Qingdao. Over marine areas, anthropogenic elements (Zn, As, and Cd) occasionally exceeded coastal levels, with coal combustion remaining dominant (40.8&amp;ndash;75.5 %). Ship emissions became especially prominent, contributing 79.3 % of V and 63.3 % of Ni offshore. Southeasterly winds transported ship-derived pollutants coastward, markedly increasing Fe (21.2 %) and Mn (14.0 %) compared to spring (1.9 % and 1.8 %, respectively). These results reveal distinct seasonal shifts in TE source across land-sea gradients, highlighting growing anthropogenic impacts, particularly from coal combustion and maritime shipping on marine aerosols. Quantifying these contributions helps assess marine biogeochemical impacts and supports targeted pollution control.</p>
</abstract>
<counts><page-count count="26"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>National Natural Science Foundation of China</funding-source>
<award-id>Cruise No. NORC2018-001</award-id>
<award-id>No. 42475119</award-id>
<award-id>No. 41605114</award-id>
</award-group>
<award-group id="gs2">
<funding-source>Natural Science Foundation of Shandong Province</funding-source>
<award-id>No. ZR2024MD016</award-id>
</award-group>
</funding-group>
</article-meta>
</front>
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