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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2025-1167</article-id>
<title-group>
<article-title>Sensitivity of Simulated Ammonia Fluxes in Rocky Mountain National Park to Measurement Time Resolution and Meteorological Inputs</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Naimie</surname>
<given-names>Lillian E.</given-names>
<ext-link>https://orcid.org/0009-0002-0451-0895</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pan</surname>
<given-names>Da</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sullivan</surname>
<given-names>Amy P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Walker</surname>
<given-names>John T.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Djurkovic</surname>
<given-names>Aleksandra</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schichtel</surname>
<given-names>Bret A.</given-names>
<ext-link>https://orcid.org/0000-0002-5512-8082</ext-link>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Collett Jr.</surname>
<given-names>Jeffrey L.</given-names>
<ext-link>https://orcid.org/0000-0001-9180-508X</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Atmospheric Science, Colorado State University, Fort Collins, CO 80523, USA</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>United States Environmental Protection Agency, Office of Research and Development, Durham, NC 27709, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Cooperative Institute for Research in the Atmosphere, Colorado State University, Fort Collins, CO 80523, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>US National Park Service, Air Resource Division, Lakewood, CO 80225-0287, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>28</day>
<month>03</month>
<year>2025</year>
</pub-date>
<volume>2025</volume>
<fpage>1</fpage>
<lpage>26</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2025 Lillian E. Naimie et al.</copyright-statement>
<copyright-year>2025</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-1167/">This article is available from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-1167/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-1167/egusphere-2025-1167.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-1167/egusphere-2025-1167.pdf</self-uri>
<abstract>
<p>Gaseous ammonia (NH&lt;sub&gt;3&lt;/sub&gt;) is an important precursor for secondary aerosol formation and contributes to reactive nitrogen deposition. NH&lt;sub&gt;3&lt;/sub&gt; dry deposition is rarely quantified due to the complex bidirectional nature of NH&lt;sub&gt;3&lt;/sub&gt; atmosphere-surface exchange and lack of high time-resolution in situ NH&lt;sub&gt;3&lt;/sub&gt; concentration and meteorological measurements. To better quantify NH&lt;sub&gt;3&lt;/sub&gt; dry deposition, measurements of NH&lt;sub&gt;3&lt;/sub&gt; were made above a subalpine forest canopy in Rocky Mountain National Park (RMNP) and used in situ micrometeorology to simulate bidirectional fluxes. NH&lt;sub&gt;3&lt;/sub&gt; dry deposition was largest during the summer, with 48 % of annual net NH&lt;sub&gt;3&lt;/sub&gt; dry deposition occurring in June, July, and August. A net annual dry deposition estimated using measured 30-minute NH&lt;sub&gt;3&lt;/sub&gt; concentrations and in situ meteorological data, accounted for 6 % of total RMNP reactive inorganic N deposition. Because in situ, high-time resolution concentration and meteorological data are often unavailable, the impact on estimated deposition from more commonly available input data was evaluated. Fluxes simulated with biweekly NH&lt;sub&gt;3&lt;/sub&gt; concentrations, commonly available from NH&lt;sub&gt;3&lt;/sub&gt; monitoring networks, underestimated NH&lt;sub&gt;3&lt;/sub&gt; dry deposition by 29 %. These fluxes were strongly correlated with 30-minute fluxes integrated to a biweekly basis (&lt;em&gt;R&lt;/em&gt;&lt;sup&gt;2&lt;/sup&gt; = 0.89) indicating that a correction factor could be applied to mitigate the observed bias. Application of an average NH&lt;sub&gt;3&lt;/sub&gt; diel concentration pattern to the biweekly NH&lt;sub&gt;3&lt;/sub&gt; concentration data removed the observed low bias. Annual NH&lt;sub&gt;3&lt;/sub&gt; dry deposition from fluxes simulated with reanalysis meteorological inputs exceeded simulations using in situ meteorology measurements by 59 %.</p>
</abstract>
<counts><page-count count="26"/></counts>
<funding-group>
<award-group id="gs1">
<funding-source>U.S. Environmental Protection Agency</funding-source>
<award-id>#2237</award-id>
</award-group>
</funding-group>
</article-meta>
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