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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2025-1095</article-id>
<title-group>
<article-title>A thousand inversions to determine European SF&lt;sub&gt;6&lt;/sub&gt; emissions from 2005 to 2021</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Vojta</surname>
<given-names>Martin</given-names>
<ext-link>https://orcid.org/0000-0001-8386-5381</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Plach</surname>
<given-names>Andreas</given-names>
<ext-link>https://orcid.org/0000-0003-4899-5871</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Thompson</surname>
<given-names>Rona L.</given-names>
<ext-link>https://orcid.org/0000-0001-9485-7176</ext-link>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Purohit</surname>
<given-names>Pallav</given-names>
<ext-link>https://orcid.org/0000-0002-7265-6960</ext-link>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Stanley</surname>
<given-names>Kieran</given-names>
<ext-link>https://orcid.org/0000-0003-3388-0932</ext-link>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>O’Doherty</surname>
<given-names>Simon</given-names>
<ext-link>https://orcid.org/0000-0002-4051-6760</ext-link>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Young</surname>
<given-names>Dickon</given-names>
<ext-link>https://orcid.org/0000-0002-6723-3138</ext-link>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pitt</surname>
<given-names>Joe</given-names>
<ext-link>https://orcid.org/0000-0002-8660-5136</ext-link>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lan</surname>
<given-names>Xin</given-names>
<ext-link>https://orcid.org/0000-0001-6327-6950</ext-link>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Stohl</surname>
<given-names>Andreas</given-names>
<ext-link>https://orcid.org/0000-0002-2524-5755</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Meteorology and Geophysics, University of Vienna, Vienna, Austria</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Chemistry, University of Crete, Crete, Greece</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>NILU, Kjeller, Norway</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>International Institute for Applied Systems Analysis (IIASA), Laxenburg, Austria</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>School of Chemistry, University of Bristol, Bristol, United Kingdom</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>CIRES, University of Colorado, Boulder, CO, USA</addr-line>
</aff>
<aff id="aff7">
<label>7</label>
<addr-line>NOAA Global Monitoring Laboratory, Boulder, CO, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>20</day>
<month>03</month>
<year>2025</year>
</pub-date>
<volume>2025</volume>
<fpage>1</fpage>
<lpage>64</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2025 Martin Vojta et al.</copyright-statement>
<copyright-year>2025</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-1095/">This article is available from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-1095/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2025/egusphere-2025-1095/egusphere-2025-1095.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2025/egusphere-2025-1095/egusphere-2025-1095.pdf</self-uri>
<abstract>
<p>We determine European emissions of sulfur hexafluoride (SF&lt;sub&gt;6&lt;/sub&gt;) from 2005 to 2021 using a large ensemble of atmospheric inversions. To assess uncertainty, we systematically vary key inversion parameters across 986 sensitivity tests and apply a Monte Carlo approach to randomly combine these parameters in 1,003 additional inversions. Our analysis focuses on high-emitting countries with robust observational coverage &amp;mdash; UK, Germany, France, and Italy &amp;mdash; while also examining aggregated EU-27 emissions.&lt;/p&gt;
&lt;p&gt;SF&lt;sub&gt;6&lt;/sub&gt; emissions declined across all studied regions except Italy, largely attributed to EU F-gas regulations (2006, 2014), however, national reports underestimated emissions: (i) UK emissions dropped from 65 (&amp;plusmn;13) t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt; in 2008 to 20 (&amp;plusmn;6) t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt; in 2018, aligning with the reports from 2018 onward; (ii) French emissions fell from 88 (&amp;plusmn;37) t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt; (2005) to 51 (&amp;plusmn;28) t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt; (2021), exceeding reports by 73 %; (iii) Italian emissions fluctuated (31&amp;ndash;67 t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt;), surpassing reports by 88 %; (iv) German emissions declined from 166 (&amp;plusmn;41) t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt; (2005) to 95 (&amp;plusmn;11) t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt; (2021), aligning reasonably well with reports; (v) EU-27 emissions decreased from 484 (&amp;plusmn;213) t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt; (2005) to 255 (&amp;plusmn;58) t yr&lt;sup&gt;&amp;minus;1&lt;/sup&gt; (2021), exceeding reports by 40 %. A substantial drop from 2017 to 2018 mirrored the trend in southern Germany, suggesting regional actions were taken as the 2014 EU regulation took effect.&lt;/p&gt;
&lt;p&gt;Our sensitivity tests highlight the crucial role of dense monitoring networks in improving inversion reliability. The UK system expansions (2012, 2014) significantly enhanced result robustness, demonstrating the importance of comprehensive observational networks in refining emission estimates.</p>
</abstract>
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