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<front>
<journal-meta>
<journal-id journal-id-type="publisher">EGUsphere</journal-id>
<journal-title-group>
<journal-title>EGUsphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">EGUsphere</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">EGUsphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub"></issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/egusphere-2024-3410</article-id>
<title-group>
<article-title>BVOC and speciated monoterpene concentrations and fluxes at a Scandinavian boreal forest</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Petersen</surname>
<given-names>Ross Charles</given-names>
<ext-link>https://orcid.org/0009-0005-6147-7499</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Holst</surname>
<given-names>Thomas</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wu</surname>
<given-names>Cheng</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Krejci</surname>
<given-names>Radovan</given-names>
<ext-link>https://orcid.org/0000-0002-9384-9702</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Chan</surname>
<given-names>Jeremy</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Mohr</surname>
<given-names>Claudia</given-names>
<ext-link>https://orcid.org/0000-0002-3291-9295</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
<xref ref-type="aff" rid="aff8">
<sup>8</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rinne</surname>
<given-names>Janne</given-names>
<ext-link>https://orcid.org/0000-0003-1168-7138</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Physical Geography and Ecosystem Science, Lund University, Lund, Sweden</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Environmental Science, Stockholm University, Stockholm, Sweden</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Bolin Centre for Climate Research, Stockholm University, 11418, Stockholm, Sweden</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Terrestrial Ecology Section, Department of Biology, University of Copenhagen, Universitetsparken 15, DK-2100 Copenhagen Ø, Denmark</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Bioeconomy and Environment, Natural Resources Institute Finland (Luke), Helsinki, Finland</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>now at: Department of Chemistry and Molecular Biology, University of Gothenburg, 41296, Gothenburg, Sweden</addr-line>
</aff>
<aff id="aff7">
<label>7</label>
<addr-line>now at: Department of Environmental Systems Science, ETH Zürich, 8006 Zürich, Switzerland</addr-line>
</aff>
<aff id="aff8">
<label>8</label>
<addr-line>now at: PSI Center for Energy and Environmental Sciences, Paul Scherrer Institute, 5232 Villigen, Switzerland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>12</day>
<month>12</month>
<year>2024</year>
</pub-date>
<volume>2024</volume>
<fpage>1</fpage>
<lpage>45</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2024 Ross Charles Petersen et al.</copyright-statement>
<copyright-year>2024</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2024/egusphere-2024-3410/">This article is available from https://egusphere.copernicus.org/preprints/2024/egusphere-2024-3410/</self-uri>
<self-uri xlink:href="https://egusphere.copernicus.org/preprints/2024/egusphere-2024-3410/egusphere-2024-3410.pdf">The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2024/egusphere-2024-3410/egusphere-2024-3410.pdf</self-uri>
<abstract>
<p>Boreal forests emit terpenoid biogenic volatile organic compounds (BVOCs) that significantly impact atmospheric chemistry. Our understanding of the variation of BVOC species emitted from boreal ecosystems is based on relatively few datasets, especially at the ecosystem-level. We conducted measurements to obtain BVOC flux observations above the boreal forest at the ICOS (Integrated Carbon Observation System) station Norunda in central Sweden. The goal was to study concentrations and fluxes of terpenoids, including isoprene, speciated monoterpenes (MT), and sesquiterpenes (SQT), during a Scandinavian summer. High-frequency (10 Hz) measurements from a Vocus proton-transfer-reaction time-of-flight mass spectrometer (Vocus PTR-ToF-MS) were used to quantify a wide range of BVOC fluxes, including total MT, using the eddy-covariance (EC) method. Surface-layer-gradient (SLG) flux measurements were performed on selected daytime sampling periods, using thermal-desorption adsorbent tube sampling, to establish speciated MT fluxes. The impact of chemical degradation on measured terpenoid fluxes relative to surface exchange rates (F/E) was also investigated using stochastic Lagrangian transport modeling in forest-canopy. While the impact on isoprene was within EC-flux uncertainty (F&lt;sub&gt;ISO&lt;/sub&gt;/E&lt;sub&gt;ISO&lt;/sub&gt;&amp;lt;5 %), the effect on SQT and nighttime MT was significant, with average F/E-ratios for nighttime F&lt;sub&gt;MT&lt;/sub&gt;/E&lt;sub&gt;MT&lt;/sub&gt;=ca.0.9 (0.87&amp;ndash;0.93), nighttime F&lt;sub&gt;SQT&lt;/sub&gt;/E&lt;sub&gt;SQT&lt;/sub&gt;=0.35 (0.31&amp;ndash;0.41) and daytime F&lt;sub&gt;SQT&lt;/sub&gt;/E&lt;sub&gt;SQT&lt;/sub&gt;=0.41 (0.37&amp;ndash;0.47). The main compounds contributing to MT flux were &amp;alpha;-pinene and &amp;Delta;&lt;sup&gt;3&lt;/sup&gt;-carene. Summer shifts in speciated MT emissions for &amp;Delta;&lt;sup&gt;3&lt;/sup&gt;-carene were detected, indicating that closer attention to seasonality of individual MT species in BVOC emission and climate models is warranted.</p>
</abstract>
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