EGUsphere

Copernicus Publications

Göttingen, Germany

10.5194/egusphere-2022-1455

A mechanism of post-depositional processes affecting chlorine and its isotope in the upper snowpack of High Antarctic Plateau

Giraud

Xavier

https://orcid.org/0000-0001-5067-8176

¹ Baroni

Mélanie

¹ Traversi

Rita

https://orcid.org/0000-0002-9790-2195

Aix Marseille Univ, CNRS, IRD, INRAE, Coll France, CEREGE, Aix-en-Provence, 13100, France

Dept. of Chemistry Ugo Schiff, University of Florence, Florence, I-50019, Italy

04 01 2023

2023 1 36

2023

This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit https://creativecommons.org/licenses/by/4.0/

This article is available from https://egusphere.copernicus.org/preprints/2023/egusphere-2022-1455/

The full text article is available as a PDF file from https://egusphere.copernicus.org/preprints/2023/egusphere-2022-1455/egusphere-2022-1455.pdf

The main purpose of this work is to propose a mechanism of post-depositional processes affecting chlorine and its chlorine-36 cosmogenic nuclide in the upper snowpack of the High Antarctic Plateau. We suggest that the observed decrease of total chlorine content in the upper meters of the snowpack is due to a progressive release of the HCl content from ice. We also propose a consistent framework, combining diffusion in bulk ice and snow microstructure. The observation of the low chlorine content in ice at depth leads to the robust hypothesis that the chemical equilibrium of chlorine between the ice and the snowpack interstitial air (SIA) is close to zero. HCl is thought to diffuse in ice, and to be progressively released in the SIA, and exported to the Antarctic atmosphere by the wind-ventilation. The time required to expel all the mobile species of chlorine (i.e., HCl) from snow depends on the diffusion coefficient of chlorine in ice combined with the snow grain size and its evolution with depth. This work is synthesised in a model combining the microstructure evolution of the upper meters of a snowpack (changes in mean snow grain size) and the diffusion of chlorine in ice applied to single spherical grains. The variability observed in chloride concentration profiles with depth, at a same site but different sampling time or different snow pits, or among different sites of the High Antarctic Plateau, is mostly due to the variations in initial concentrations in HCl and sodium chloride (NaCl) species and the snow grain size evolution. This model offers a common framework for understanding the fate of chlorine in Antarctica, from coastal to inland locations, including low accumulation sites on the plateau, far from the ocean. Applications of this post-depositional model to chlorine and to 36Cl allows to picture a recycling mechanism of chlorine at the scale of Antarctica. In particular, the 36Cl concentration in the surface snow of the Vostok site illustrates this recycling mechanism and the persistent contamination of inland Antarctica by anthropogenic 36Cl originating from the marine nuclear tests of the 1950s to the 1970s.